| 161730-95-6

• CAS: 161730-95-6
• 化学式: C₁₉H₂₆ClN₂ORhS
• 分子量: 468.853
• InChiKey: PBFBAFYEWOYJJE-ONEVTFJLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 、 N-(n-propyl)-N'-benzoylthiourea 以 二氯甲烷 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Anchoring rhodium(I) on benzoylthiourea-functionalized silica xerogels. Production of recyclable hydroformylation catalysts and the crystal structure of the model compound [Rh(cod)(Hbztu)Cl]

  摘要：

  Two benzoylthiourea-functionalized silica xerogels, 4.5SiO(2).SiO3/2(CH2)(3)NHC(S)NHC(O)Ph (XGbztu) and SiO3/2 (CH2)(3)NHC(S)NHC(O)Ph (XGbztu*) have been prepared from (EtO)(3)Si(CH2)(3)NHC(S)NHC(O)Ph by the sol-gel process. They are able to bind rhodium(I) species giving the composite materials Rh/XGbztu and Rh/XGbztu*, which are very active insoluble and recoverable catalysts for the hydroformylation of styrene. The anchored species undergo major changes during the catalytic cycles, particularly in the Rh/XGbztu system, whose iso/normal selectivity ratio gradually increased in the first five runs. Furthermore, CH3(CH2)(2)NHC(S)NHC(O)Ph (HBztu) has been studied as a model of the surface binding function. The structure of [Rh(cod)(Hbztu)Cl](1), which represents a suitable molecular model for the anchored complexes, has been determined by X-ray diffraction.

  DOI：

  10.1016/0022-328x(94)00009-2