Synthesis, Structural Characterization, and Properties of Aluminum (III) meso-Tetraphenylporphyrin Complexes Axially Bonded to Phosphinate Anions
摘要:
Aluminum (III) meso-tetraphenylporphyrins axially bonded to phosphinate anions have been synthesized and characterized by NMR and UV-visible spectroscopy, single-crystal X-ray diffraction, and FAB(+) mass spectrometry. According to the solvent and the size of the anion, these compounds are able to self-assemble in two different manners.
Synthesis, Structural Characterization, and Properties of Aluminum (III) meso-Tetraphenylporphyrin Complexes Axially Bonded to Phosphinate Anions
摘要:
Aluminum (III) meso-tetraphenylporphyrins axially bonded to phosphinate anions have been synthesized and characterized by NMR and UV-visible spectroscopy, single-crystal X-ray diffraction, and FAB(+) mass spectrometry. According to the solvent and the size of the anion, these compounds are able to self-assemble in two different manners.