di[(2-(o-anisyl)-6-(o-2-phenoxide)phenyl)(indenide)samarium(III)] | 1208507-79-2

• 英文名称: di[(2-(o-anisyl)-6-(o-2-phenoxide)phenyl)(indenide)samarium(III)]
• CAS: 1208507-79-2
• 化学式: C₅₆H₄₂O₄Sm₂
• 分子量: 1079.67
• InChiKey: BAFAASIIDNMFPA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  potassium indenyl 、 (2,6-di(o-anisol)phenyl)lithium 、 氯化钐 以 四氢呋喃 为溶剂， 以10%的产率得到di[(2-(o-anisyl)-6-(o-2-phenoxide)phenyl)(indenide)samarium(III)]
  参考文献：
  名称：

  Synthesis and structural characterization of terphenyl based mono(indenide) compounds of the rare-earth elements

  摘要：

  The synthesis and X-ray crystal structure determination of the mono(indenide) rare-earth compounds [(DanipO)(Ind)Ln](2) (Ln = Sm: 1; Ln = Yb: 2) are reported (DanipO = 2-(o-anisyl)-6-(o-2-phenoxide)phenyl, Ind = indenide). Reaction of DanipLi (Danip = 2,6-di-o-anisolphenyl) with the corresponding lanthanide trichloride in tetrahydrofuran followed by addition of two equiv of KInd in tetrahydrofuran at -25 degrees C yields compounds 1 and 2 in approximately 10-20% yield. The molecular structures of 1 and 2 show an unsolvated dimeric half-sandwich compound and a formally dianionic partially demethylated mixed arylether/aryloxide terphenyl ligand (= DanipO). (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.10.018