Fe(1,2-bis(diphenylphosphino)-3,4,5-trimethylcyclopentadienyl)2Cr(CO)4 | 211688-11-8

• 英文名称: Fe(1,2-bis(diphenylphosphino)-3,4,5-trimethylcyclopentadienyl)2Cr(CO)4
• CAS: 211688-11-8
• 化学式: C₆₈H₅₈CrFeO₄P₄
• 分子量: 1170.94
• InChiKey: TUZMBZUOJAJVDN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetracarbonylnorbornadienchrom 、 1,1'-diphenylphosphinooctamethylferrocene 以 甲苯 为溶剂， 以76%的产率得到Fe(1,2-bis(diphenylphosphino)-3,4,5-trimethylcyclopentadienyl)2Cr(CO)4
  参考文献：
  名称：

  Ferrocenic polyphosphines and polythioethers: synthesis, reactivity and structure

  摘要：

  The new ferrocenic polyphosphines [C5Me3-1,2-(PPh2)(2)](C5H5)Fe 2, [C5Me3-1,2-(PPh2)(2)](2),Fe 3, [C5Me3-1,2-(PPh2)(2)][C5Me4(PPh2)]Fe 4 and polythioethers [C5Me3-1,2-(SCH2CH2CH3)2](2)Fe 6 and [C5Me3-1,2-(SCH2CH2CH3)(2)](C5H5)Fe 7 have been prepared. The X-ray crystal structures of 3 and 6 have been determined. Some aspects of the reactivity of compounds 2, 3 and 4 are reported (P(III)-->P(V) transformation, chelating properties) as well as the X-ray structure of [C5Me3-1,2(PPh2)(2)W(CO)(4)](C5H5)Fe 15. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00551-8