FeCl2(bis(benzimidazol-2-yl-methyl)ether) | 526191-03-7

• 英文名称: FeCl2(bis(benzimidazol-2-yl-methyl)ether)
• CAS: 526191-03-7
• 化学式: C₁₆H₁₄Cl₂FeN₄O
• 分子量: 405.066
• InChiKey: OWHNXGUKVVXCKK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Fe4Cl8(THF)6 、 1,3-bis(1H-benzimidazol-2-yl)-2-oxapropane 以 甲苯 为溶剂， 以86%的产率得到FeCl2(bis(benzimidazol-2-yl-methyl)ether)
  参考文献：
  名称：

  Synthesis and structural characterization of iron(II) derivatives of heterocyclic tridentate amines

  摘要：

  Compounds of general formula FeX2(L) {L=2,6-bis(3,5-dimethyl-N-pyrazolyl)pyridine, C15H17N5; bis[3,5-dimethyl-N-pyrazolyl)methyl]-isopropylamine, C15H25N5; bis(benzimidazol-2-yl-methyl)amine, C16H15N5, 1,3-bis(benzimidazolyl)propane, C17H16N4; bis(benzimidazolyl-2-methyl)ether, C16H14N4O; bis(benzimidazolyl-2-methyl)thioether, C16H14N4S} have been synthesized by reacting the amine with Fe4Cl8(THF)(6) or FeI2(CO)(4) in toluene. The complexes FeCl2(Cl15H17N5).MeCN and FeCl2(C16H15N5)(MeOH) have been characterized by single crystal X-ray diffraction together with the parent triamines, C15H17N5 and C16H15N5, for comparison. The reaction of FeI2(CO)(4) with bis(benzimidazolyl-2-methyl)thioether, C16H14N4S, led to the product of partial carbonyl substitution Fel(2)(CO)(2)(C16H14N4S). (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01304-x