[Re(p-tolylimido)Cl3(triphenylarsine)2] | 1245575-85-2

• 英文名称: [Re(p-tolylimido)Cl3(triphenylarsine)2]
• 英文别名: [Re(p-methylphenylimido)Cl3(triphenylarsine)2]
• CAS: 1245575-85-2
• 化学式: C₄₃H₃₇As₂Cl₃NRe
• 分子量: 1010.18
• InChiKey: HSFZPZCRYSSZQF-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  乙烷,三氯氟- 、 ReOCl3(triphenylarsine)2 以 苯 为溶剂， 以60%的产率得到[Re(p-tolylimido)Cl3(triphenylarsine)2]
  参考文献：
  名称：

  p-Tolylimido rhenium(V) complexes – Synthesis, X-ray studies, spectroscopic characterization and DFT calculations

  摘要：

  The p-tolylimido rhenium(V) complexes [Re(p-NC6H4CH3)X-3(EPh3)(2)] (X = Cl, Br; E = As, P) and [Re(p-NC6H4CH3)Cl-2(hmpbta)(PPh3)]center dot MeCN have been synthesized and characterized spectroscopically and structurally. The electronic spectra of [Re(p-NC6H4CH3)Cl-3(PPh3)(2)] and [Re(P-NC6H4CH3)Cl-2(hmpbta)(PPh3)](Hhmpbta-2-(2'-hydroxy-5'-methylPhenyl)benzotriazole) were investigated at the TDDFT level employing B3LYP functional in combination with LANL2DZ. Additional information about bonding between the rhenium atom and p-tolylimido ligand in the complexes [Re(p-NC6H4CH3)Cl-3(PPh3)(2)] and [Re(p-NC6H4CH3)Cl-2(hmpbta)(PPh3)] was obtained by NBO analysis. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.05.011