mer-(PMe3)3Ir(SC3H2N(CH3))Cl | 1384752-20-8

• 英文名称: mer-(PMe3)3Ir(SC3H2N(CH3))Cl
• CAS: 1384752-20-8
• 化学式: C₁₃H₃₂ClIrNP₃S
• 分子量: 555.064
• InChiKey: VCQKIXJPWHWLJB-GLUPTGNJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5-甲基噻唑 、 [Ir(COD)(PMe₃)₃]Cl 以 均三甲苯 为溶剂， 以73%的产率得到mer-(PMe3)3Ir(SC3H2N(CH3))Cl
  参考文献：
  名称：

  Reactions of [Ir(COD)(PMe3)3]Cl with heteroaromatic compounds: Formation of an iridathiacycle, an iridaselenacycle and iridaazathiacycles

  摘要：

  Reactions between [Ir(COD)(PMe3)(3)]Cl, 1, and the heteroaromatic compounds thiophene, selenophene and thiazole (and substituted thiazoles) are reported. Compound 1 acts as a convenient source of the very electron-rich "Ir(PMe3)(3)Cl" which is very active for oxidative addition reactions. All of the heteroaromatic compounds mentioned add via C-S or C-Se oxidative addition resulting in the insertion of the iridium forming 6-membered thia- or selena-iridacycles.[GRAPHICS]. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.05.003