RuCl(pentenyl)(CO)(PMe3)3 | 1223097-31-1

• 英文名称: RuCl(pentenyl)(CO)(PMe3)3
• CAS: 1223097-31-1
• 化学式: C₁₅H₃₆ClOP₃Ru
• 分子量: 461.895
• InChiKey: GJVOUMPWRSTEPI-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  Ru(pentenyl)Cl(CO)(PPh3)2 、 三甲基膦 以 四氢呋喃 、 二氯甲烷 为溶剂， 以73%的产率得到RuCl(pentenyl)(CO)(PMe3)3
  参考文献：
  名称：

  Synthesis and characterization of (CHCH)n-bridged (n=1, 2, 3) heterobimetallic and trimetallic ferrocene–ruthenium complexes

  摘要：

  A series of heterobinuclear ferrocene-ruthenium complexes Fc(CH=CH)(n)RuCl(CO)(PMe3)(3) (n = 1, 3; n = 2, 12), Fc(CH=CH)RuCl(CO)(Py)(PPh3)(2) (4), and trimetallic Fc(CH=CH)RuCl(CO)(PPh3)(2)(Py-E-(CH=CH)Fc) (6) have been prepared. The length of the molecular rods is extended by successive insertion of CH=CH spacers in the bridging ligands or the ancillary ligands. The respective products have been fully characterized and the structures of 3 and 12 have been established by X-ray crystallography. Electrochemical studies have revealed that ethenyl heterobimetallic complexes display two successive one-electron processes, and that intermetallic electronic communication between the two endgroups is attenuated with the increase of the length of the conjugated bridge. The electrochemical behavior of the trimetallic complex reveals strong electronic communication between ruthenium and ferrocene transmitted through the ethenyl bridge, however, it also reveals a very weak interaction between ruthenium and ferrocene transmitted through the (E)-CH=CH-Py bridge. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.12.019