[(N-methyl-N-2-hydroxybenzyl-2-aminoethyl-2-pyridine(-1H))₂Ni₂Mn(OAc)₄(H₂O)₂] | 944541-00-8

• 英文名称: [(N-methyl-N-2-hydroxybenzyl-2-aminoethyl-2-pyridine(-1H))₂Ni₂Mn(OAc)₄(H₂O)₂]
• 英文别名: [(N-methyl-N-(2-hydroxybenzyl)-2-aminoethyl-2-pyridine(-1H))2Ni2Mn(μ2-1,3-acetato)2(μ2-1,1-acetato)2(H2O)2]
• CAS: 944541-00-8
• 化学式: C₃₈H₅₀MnN₄Ni₂O₁₂
• 分子量: 927.153
• InChiKey: IHBQHLVRAUHZGL-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-methyl-N-2-hydroxybenzyl-2-aminoethyl-2-pyridine 、 manganese (II) acetate tetrahydrate 、 nickel(II) acetate tetrahydrate 以 甲醇 为溶剂， 生成 [(N-methyl-N-2-hydroxybenzyl-2-aminoethyl-2-pyridine(-1H))₂Ni₂Mn(OAc)₄(H₂O)₂]
  参考文献：
  名称：

  Phenolate- and Acetate (Both μ₂-1,1 and μ₂-1,3 Mode)-Bridged Face-Shared Trioctahedral Linear Ni^II₃, Ni^II₂M^II (M = Mn, Co) Complexes:  Ferro- and Antiferromagnetic Coupling

  摘要：

  The complexes [(L)(2)(Ni2MII)-M-II(mu(2)-1,3-OAc)(2)(mu(2)-1,1-OAc)(2)(S)(2)]center dot xMeOH [HL = N-methyl-N-(2-hydroxybenzyl)-2-aminoethyl-2-pyridine; M = Ni, S = MeOH, x = 6 (1); M = Mn, S = H2O, x = 0 (2); M = Co, S = MeOH, x = 6 (3)] have been synthesized. Crystal structures reveal that three octahedral M-II ions form a linear array with two terminal moieties {(L)Ni-II(mu(2)-1,3-OAc)(mu(2)-1,1-OAc)(MeOH/H2O)}(-) in a facial donor set and a central M-II ion which is connected to the terminal ions via bridging phenolate and two types of bridging acetates. Magnetic measurements reveal that the Ni-3(II) and (Ni2CoII)-Co-II centers are ferromagnetically and (Ni2MnII)-Mn-II center is antiferromagnetically coupled. An attempt has been made to rationalize the observed magneto-structural behavior.

  DOI：

  10.1021/ic0623157