Fe[η5-C5H4(1-C6H2(CH2NMe2)2-3,5-4-PdCl)]2 | 640298-75-5

• 英文名称: Fe[η5-C5H4(1-C6H2(CH2NMe2)2-3,5-4-PdCl)]2
• CAS: 640298-75-5
• 化学式: C₃₄H₄₄Cl₂FeN₄Pd₂
• 分子量: 848.343
• InChiKey: ZHBCPAQKVMWRIJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Fe(η5-C5H4-4-(C6H3(CH2NMe2)2-2,6))2] 、 trans-dichlorobis(dimethylsulfide)palladium(II) 在 叔丁基锂 作用下， 以 乙醚 为溶剂， 以53%的产率得到Fe[η5-C5H4(1-C6H2(CH2NMe2)2-3,5-4-PdCl)]2
  参考文献：
  名称：

  Ferrocene-bridged Pd–NCN pincer complexes

  摘要：

  The meta-diaminoaryl ferrocene Fe[eta(5)-C5H4(NCNH)](2) [NCNH = 1-C6H3(CH2NMe2)(2)-3,5] (3) can be synthesised by the reaction of Fe[eta(5)-C5H4(ZnCl)](2) (1) with I-C6H3(CH2NMe2)(2)-3,5 (2) in a 1:2 molar ratio in the presence of catalytic amounts of [Pd(PPh3)(2)]. The two meta-dimaminoaryl NCNH pincer units in 3 can be used to assemble multimetallic complexes. Thus, 3 produces on reaction with (BuLi)-Bu-t and (Me2S)(2)PdCl2 trimetallic Fe[eta(5)-C5H4(NCN-4-PdCl)](2) {NCN = 1-C6H2(CH2NMe2)(2)-3,5} (6) along with heterobimetallic Fe[eta(5)-C5H4(NCNH)][eta(5)-C5H4(NCN-4-PdCl)] (5). Complex 6 contains two bis-ortho-chelated pincer NCN-PdCl units, whereas 5 possesses one bis-ortho-chelated NCN pincer entity and one non-metallated NCNH moiety. Complex 6 is the first example in organometallic chemistry in which two bis-ortho-chelated diaminoaryl palladium units are bridged via the respective para C-atoms spanned by a redox-active ferrocenyl building block. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00753-8