zinc-5,15-dichloro-10-[4,4'-bipyridinium-hexafluorophosphate]-porphyrinate | 232925-84-7

• 英文名称: zinc-5,15-dichloro-10-[4,4'-bipyridinium-hexafluorophosphate]-porphyrinate
• CAS: 232925-84-7
• 化学式: C₄₆H₄₉Cl₂N₆Zn*F₆P
• 分子量: 967.195
• InChiKey: INQSQUDZQZCWDW-VSWFEVINSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  zinc-5,15-dichloro-10-[4,4'-bipyridinium-hexafluorophosphate]-porphyrinate 以 1,2-二氯乙烷 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  A Polycationic Zinc-5,15-dichlorooctaethylporphyrinate-viologen Wire

  摘要：

  Electropolymerization of zinc-10-bipyridinium-octaethyl-porphyrinate by cyclic scanning between -0.6 and +1.6 V yields a zigzag configured polymer, which appears as swollen, vesicular bilayer on atomic force micrographs. The same procedure leads to micrometer-long wire-shaped linear polymers, if the 5,15-methine bridge carbon atoms are blocked by chlorine substituents. The wires come in two parallel strands originating from antiparallel face-to-face dimers in the solution.

  DOI：

  10.1021/ja984404r
• 作为产物：
  描述：

  4,4'-联吡啶 、 zinc 5,15-dichloro-β-octaethylporphyrin 、 tetraethylammonium hexafluorophosphate 以 二氯甲烷 、 乙腈 为溶剂， 以94%的产率得到zinc-5,15-dichloro-10-[4,4'-bipyridinium-hexafluorophosphate]-porphyrinate
  参考文献：
  名称：

  A Polycationic Zinc-5,15-dichlorooctaethylporphyrinate-viologen Wire

  摘要：

  Electropolymerization of zinc-10-bipyridinium-octaethyl-porphyrinate by cyclic scanning between -0.6 and +1.6 V yields a zigzag configured polymer, which appears as swollen, vesicular bilayer on atomic force micrographs. The same procedure leads to micrometer-long wire-shaped linear polymers, if the 5,15-methine bridge carbon atoms are blocked by chlorine substituents. The wires come in two parallel strands originating from antiparallel face-to-face dimers in the solution.

  DOI：

  10.1021/ja984404r