| 211321-35-6

• CAS: 211321-35-6
• 化学式: C₆H₁₆LiN₂*C₁₈H₄₈GaS₂Si₄
• 分子量: 633.924
• InChiKey: HZOFBZWKGRSGFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrakis[bis(trimethylsilyl)methyl]digallane(4) 、 methylthiomethyllithium *TMEDA 以 正戊烷 为溶剂， 以36%的产率得到
  参考文献：
  名称：

  Untersuchungen zur Carbeninsertion in Al-Al-, Ga-Ga- und In-In-Bindungen

  摘要：

  Tetrakis[bis(trimethylsilyl)methyl] dialane(4) 1 reacts with methylthiomethyl lithium LiCH2SMe by the formation of lithium thiomethanolate LiSMe and the insertion of the remaining carbene CH2 into its Al-Al single bond. A chelating Lewis acid is formed exhibiting a central R2Al-CH2-AIR(2) group with two coordinatively unsaturated Al atoms, which coordinate the thiomethanolate anion by Al-S bonds. The product (mu-methylene) (mu-thiomethanolato)bis{bis[bis(trimethylsilyl)methyl]aluminate} (4) was characterized by a crystal structure determination and has a strongly folded Al2CS heterocycle in the molecular core. In contrast,;he corresponding compounds with Ga-Ga or In-In bonds show on treatment with methylthiomethyl lithium a fragmentation, and the carbene intermediate could not be detected in both isolated products, which were identified as [R2E(CH2SMe)(2)][Li(TMEDA)] (E = Ga: 5; E = In: 6) and LiCH(SiMe3)(2) probably formed by a metal exchange reaction.

  DOI：

  10.1002/(sici)1521-3749(199806)624:6<937::aid-zaac937>3.0.co;2-9