| 491613-31-1

• CAS: 491613-31-1
• 化学式: CF₃O₃S*C₁₅H₂₆Cl₂ReS₂
• 分子量: 676.687
• InChiKey: LMSKXVXZDABODA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 三氟甲烷磺酸甲酯 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Reactions of Dithiolate Ligands in Mononuclear Complexes of Rhenium(V). 2. Cp‘ ‘ReCl₂(η²-SC₃H₆S) and Related Derivatives

  摘要：

  The syntheses and characterizations of Cp"ReCl2(SC3H6S), 1, Cp"ReCl3(SCHMe2), 2, and Cp"ReCl2(SCHMe2)(2), 3, are reported (Cp" = C5Me4Et). Complex 2 has been characterized by an X-ray diffraction study, which confirms its mononuclear structure. Reactions of 1, 2, and 3 have been studied and compared with those characterized previously for Cp"ReCl2(SC2H4S). For example, the thermal reaction of 1 in toluene at 100 degreesC, results in the elimination of HCl and formation of a complex with a chelated thiolate/thialdehyde ligand, Cp"ReCl(SCH2CH2CH=S), 5. Complex 5 can also be synthesized at a lower temperature by the reaction of 1 with excess triethylamine. Spectroscopic characteristics and reactivity of 5 are reported.

  DOI：

  10.1021/om020626t