[(OC)5(2-trimethylsilyl-1,3-diphenylphosphirene)] | 1221746-80-0

• 英文名称: [(OC)5(2-trimethylsilyl-1,3-diphenylphosphirene)]
• CAS: 1221746-80-0
• 化学式: C₂₂H₁₉O₅PSiW
• 分子量: 606.299
• InChiKey: VLISOQAVMCAZNM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(OC)5(2-trimethylsilyl-1,3-diphenylphosphirene)] 、 水 在 N(C₄H₉)4F 作用下， 以 四氢呋喃 为溶剂， 以57%的产率得到(1,2-diphenylphosphirene)pentacarbonyltungsten
  参考文献：
  名称：

  Reactivity of 2-Silyl- and 2-Stannyl-Substituted Phosphirenes

  摘要：

  Two methodologies have been tested for the functionalization of phosphirenes. In the first one, the C Si bond of a 2-silylphosphirene is activated by a substoichiometric quantity of fluoride ion (TBAF) in THF at -78 degrees C. Using this technique, it is possible to perform a protodesilylation or a functionalization by benzaldehyde. However, at room temperature with a stoichiometry of fluoride, a nucleophilic attack takes place at P, leading to a ring-opened fluorophosphine. Stale cross-coupling with a 2-stannylphosphirene in the presence of [PdL2] as a catalyst leads to an alkynylphosphine by [1,3] migration of tin from C to P.

  DOI：

  10.1021/om100083e
• 作为产物：
  描述：

  syn-[5,6-dimethyl-2,3-bis(methoxycarbonyl)-7-phenyl-7-phosphanorbornadiene]pentacarbonyltungsten 、 苯基乙炔基三甲基硅烷 以 甲苯 为溶剂， 以87%的产率得到[(OC)5(2-trimethylsilyl-1,3-diphenylphosphirene)]
  参考文献：
  名称：

  Reactivity of 2-Silyl- and 2-Stannyl-Substituted Phosphirenes

  摘要：

  Two methodologies have been tested for the functionalization of phosphirenes. In the first one, the C Si bond of a 2-silylphosphirene is activated by a substoichiometric quantity of fluoride ion (TBAF) in THF at -78 degrees C. Using this technique, it is possible to perform a protodesilylation or a functionalization by benzaldehyde. However, at room temperature with a stoichiometry of fluoride, a nucleophilic attack takes place at P, leading to a ring-opened fluorophosphine. Stale cross-coupling with a 2-stannylphosphirene in the presence of [PdL2] as a catalyst leads to an alkynylphosphine by [1,3] migration of tin from C to P.

  DOI：

  10.1021/om100083e