[(C6F5Zn)4Zn(2-chlorobenzoate)6] | 1255510-64-5

• 英文名称: [(C6F5Zn)4Zn(2-chlorobenzoate)6]
• CAS: 1255510-64-5
• 化学式: C₆₆H₂₄Cl₆F₂₀O₁₂Zn₅
• 分子量: 1928.55
• InChiKey: PRIOHSMUGAGXJU-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  Zn(C6F5)2*(toluene) 、 2-氯苯甲酸 以 甲苯 为溶剂， 以80%的产率得到[(C6F5Zn)4Zn(2-chlorobenzoate)6]
  参考文献：
  名称：

  Multinuclear Zinc Pentafluorobenzene Carboxylates: Synthesis, Characterization, and Hydrogen Storage Capability

  摘要：

  Three zinc carboxylate complexes, [(C6F5Zn)(4)-Zn(Ar-1)6]center dot 1.5 toluene, [(C6F5Zn)(4)Zn(Ar-2)(6)]center dot 2toluene, and [(Ar-3)(6)Zn-4(mu(4)-O)]center dot MeCN (where Ar-1 = 2-chlorobenzoic acid (1), Ar-2 = 2,4,6-trimethylbenzoic acid (2), and Ar-3 = 3-dimethylaminobenzoic acid (3)), have been prepared from the reaction of (C6F5)(2)Zn center dot toluene and the corresponding functionalized benzoic acid. Complexes 1-3 were structurally characterized and screened for hydrogen absorption (uptake <0.3 wt %).

  DOI：

  10.1021/om100703c