[Ru2(CO)6(μ-dppm)(μ-SiTol2)] | 423120-80-3

• 英文名称: [Ru2(CO)6(μ-dppm)(μ-SiTol2)]
• CAS: 423120-80-3
• 化学式: C₄₅H₃₆O₆P₂Ru₂Si
• 分子量: 964.95
• InChiKey: JATHLHLDXUZCMY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(4-(tert-butyl)phenyl)silane 、 [Ru2(CO)6(μ-dppm)(μ-SiTol2)] 以 甲苯 为溶剂， 生成 (Ru(CO)2(Si(p-t-BuC6H4)2H))2(μ-dppm)(μ-η2:η2-H2SiTol2)
  参考文献：
  名称：

  Interconversion among μ-Silylene, μ-Silyl, and μ-Silane Diruthenium Complexes in the Presence of Dihydrosilane

  摘要：

  Irradiation of a toluene solution of[Ru(2)(CO)(6)-(mu-dppm)(mu-SiTol(2))] (1) in the presence of an excess of Tol(2)SiH(2) produced a Ai-silyl complex, [Ru(2)(CO)(5)(SiTol(2)H)-(mu-dppm)(mu-eta(2)-HSiTol(2))] (2), which was further converted to alpha mu-silane complex, [(Ru(CO)(2)(SiTol(2)H))(2)(mu-dppm)(mu-eta(2):eta(2)-H(2)SiTol(2))] (3), quantitatively. Complex 3 released Tol(2)SiH(2) in the presence of CO to regenerate 2, which finally reverted to 1 under thermal conditions. The X-ray crystal structures of 1 and 3 were determined.

  DOI：

  10.1021/om0109814
• 作为产物：
  描述：

  Ru2(CO)5(SiTol2H)(μ-dppm)(μ-η2-SiTol2H) 、 一氧化碳 以 苯 为溶剂， 生成 [Ru2(CO)6(μ-dppm)(μ-SiTol2)]
  参考文献：
  名称：

  Interconversion among μ-Silylene, μ-Silyl, and μ-Silane Diruthenium Complexes in the Presence of Dihydrosilane

  摘要：

  Irradiation of a toluene solution of[Ru(2)(CO)(6)-(mu-dppm)(mu-SiTol(2))] (1) in the presence of an excess of Tol(2)SiH(2) produced a Ai-silyl complex, [Ru(2)(CO)(5)(SiTol(2)H)-(mu-dppm)(mu-eta(2)-HSiTol(2))] (2), which was further converted to alpha mu-silane complex, [(Ru(CO)(2)(SiTol(2)H))(2)(mu-dppm)(mu-eta(2):eta(2)-H(2)SiTol(2))] (3), quantitatively. Complex 3 released Tol(2)SiH(2) in the presence of CO to regenerate 2, which finally reverted to 1 under thermal conditions. The X-ray crystal structures of 1 and 3 were determined.

  DOI：

  10.1021/om0109814