| 1415025-05-6

• CAS: 1415025-05-6
• 化学式: C₄₄H₅₂Cl₂N₄O₁₀SmZn₂*F₆P
• 分子量: 1293.93
• InChiKey: YNJLYSIZWCOJRJ-GRBYJVQVSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 samarium(III) chloride hexahydrate 、 N,N′-bis(3-methoxy-salicylidene)cyclohexane-1,2-diamine 、 zinc(II) acetate dihydrate 以 二氯甲烷 、 水 为溶剂， 反应 26.0h， 以55%的产率得到
  参考文献：
  名称：

  Salen-type heteronuclear 3d–4f complexes engineering by anion PF6 with near-infrared (NIR) and luminescent properties

  摘要：

  Two heteronuclear 3d-4f complexes obtained by salen-type ligand N,N'-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane (H2L1) and N,N'-bis(2-hydroxy-3-methoxy benzylidene)-1,2-diaminohexane (H2L2) have been isolated. They are co-crystallized complex [Yb(ZnL1)(OAc)(2)(H2O)]center dot[Yb(ZnL1)(OAc)(3)]center dot PF6 center dot CH3OH (1), trinuclear complex [Sm(ZnL2)(2)Cl-2(H2O)(2)]center dot PF6 (2). In complexes 1 and 2 the anion PF6 called counteranion is not only a role to neutralize overall charge in the solid but also to regulate frameworks. The complexes were structurally characterized by single crystal X-ray crystallographic studies and their photophysical properties were investigated (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2012.09.017