(η2-Ph2PCH2CH2PPh2)(η5-C5Me5)Fe-CC-C6H4-4-Cl | 1247014-79-4

• 英文名称: (η2-Ph2PCH2CH2PPh2)(η5-C5Me5)Fe-CC-C6H4-4-Cl
• CAS: 1247014-79-4
• 化学式: C₄₄H₄₃ClFeP₂
• 分子量: 725.073
• InChiKey: SZXWXELFHHGAPN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  4-氯苯乙炔 、 [Fe(pentamethylcyclopentadienyl)(CO)₂Cl] 、 1,2-双(二苯基膦)乙烷 在 DBU 作用下， 以 甲醇 为溶剂， 以47%的产率得到(η2-Ph2PCH2CH2PPh2)(η5-C5Me5)Fe-CC-C6H4-4-Cl
  参考文献：
  名称：

  One-Pot Synthesis of Mononuclear Iron Alkynyl Complexes by Photolysis

  摘要：

  A new access to organoiron complexes of type (dppe)Cp*Fe-C C- Ar the easily prepared precursor (CO)(2)Cp*FeCl (5) is de.vcribed. This direct one-pot transformation realized upon UV irradiation is illustrated by various aromatic alkynes. A mechanism is also proposed for this reaction via the key intermediate[dppe)Cp*Fe(CO)][PF6](6).

  DOI：

  10.1021/om100665u