Ru4(μ-H)(μ3-Ph2P(C10H6-1,8)PPh(C6H4))(μ-CO)3(CO)7 | 705974-25-0

• 英文名称: Ru4(μ-H)(μ3-Ph2P(C10H6-1,8)PPh(C6H4))(μ-CO)3(CO)7
• CAS: 705974-25-0
• 化学式: C₄₄H₂₆O₁₀P₂Ru₄
• 分子量: 1180.91
• InChiKey: WSWIPTXMJZQJMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  十二羰基三钌 、 二氯甲烷 、 1,8-双(二苯基膦)萘 以 四氢呋喃 为溶剂， 以26%的产率得到Ru3(μ-H)(μ3-Ph2P(C10H6-1,8)PPhC6H4)(CO)8
  参考文献：
  名称：

  Reactions of 1,8-bis(diphenylphosphino)naphthalene with ruthenium cluster carbonyls: C–H and C–P bond cleavage reactions

  摘要：

  Reactions between Ru-3(CO)(12) and 1,8-bis(diphenylphosphino)naphthalene (dppn) have given the four complexes Ru-3(mu-H){mu(3)-PPh2(nap)PPh(C6H4)}(CO)(8) (1), Ru-4(mu-H){mu(3)-PPh2(nap)PPh(C6H4)}(mu-CO)(3)(CO)(7) (2) and Ru-4(mu-H)(mu(3)-C6H4){mu-PPh(nap)PPh2}(CO)(11) (3) (in refluxing thf), and Ru-4{mu(4)-P(nap)PPh2}(mu(4)-C6H4)(mu-CO)(CO)(9) (4) (in refluxing toluene) which have been characterised by single crystal X-ray studies. They have been formed by aryl C-H and aryl C-P bond cleavage reactions, presumably from an initial (unobserved) chelate dppn complex. The unchanged chelating ligand is found in Ru-3(mu-dppm)(CO)(8)(dppn) (5), obtained from Ru-3(mu-dppm)(CO)(10) and dppn in refluxing thf. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.01.022