bis(2-methylpropyl)phosphinothioylimino-bis(2-methylpropyl)-sulfido-λ5-phosphane;palladium(2+) | 227181-55-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: bis(2-methylpropyl)phosphinothioylimino-bis(2-methylpropyl)-sulfido-λ5-phosphane;palladium(2+)
• CAS: 227181-55-7
• 化学式: C₃₂H₇₂N₂P₄PdS₄
• 分子量: 843.516
• InChiKey: LJKZQTUMLYZXRY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.54
• 重原子数：
  43.0
• 可旋转键数：
  16.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  28.2
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  PP-bis(2-methylpropyl)-N-[bis(2-methylpropyl)phosphinothioyl]phosphinothioic amide 、 [PdCl2(COD)] 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 生成 bis(2-methylpropyl)phosphinothioylimino-bis(2-methylpropyl)-sulfido-λ5-phosphane;palladium(2+)
  参考文献：
  名称：

  Synthesis and coordination chemistry of tetrabutyldithioimidodiphosphinates

  摘要：

  Butyl substituted imidodithiophosphinates R2P(S)NP(S)R'(2) (R=Bu-n,Bu-t, Bu-s; R'=Bu-n,Bu-i,Bu-s) have been synthesised via an HBr elimination reaction between R2P(S)NH, and R'P-2(S)Br. The compounds were characterised spectroscopically. Crystallographic and spectroscopic studies reveal (Bu2P)-Bu-n(S)NHP(S)Bu-n(2) and (Bu2P)-Bu-s(S)NHP(S)Bu-1(2) to be hydrogen bonded transoid dimers and (Bu2P)-Bu-1(S)NHP(S)Bu-1(2) to be a transoid hydrogen bonded chain. Reactions of the imidodithiophosphinates with ZnCl2 or MCl2COD gave the coordination complexes M[R2P(S)NP(S)R'(2)], (R=Bu-n,Bu-i, Bu-s; R'=Bu-n,Bu-i, Bu-s; M=Zn, Pd: R=Bu-n,Bu-i,Bu-s, Pt). (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00343-x