[Gd(dimethylformamide-O)2(dimethylformamide-N)F4](1-) | 1351930-49-8

• 英文名称: [Gd(dimethylformamide-O)2(dimethylformamide-N)F4](1-)
• CAS: 1351930-49-8
• 化学式: C₉H₂₁F₄GdN₃O₃
• 分子量: 452.528
• InChiKey: IDJTUNYYDZNCCB-UHFFFAOYSA-J

反应信息

• 作为反应物：
  描述：

  [Gd(dimethylformamide-O)2(dimethylformamide-N)F4](1-) 以 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 [Gd(dimethylformamide)2F2](1+)
  参考文献：
  名称：

  Composition of a mixed-ligand gadolinium(III) complex in fluoride-dimethylformamide electrolyte

  摘要：

  The gadolinium(III) complex formed in a fluoride-dimethylformamide (DMF) electrolyte was studied by linear-sweep voltammetry and IR spectroscopy. The composition of the mixed-ligand complex formed was found to correspond to the component ratios Gd: DMF: F = 1: 3: 4. It has been found that the coordination link in the complex is via two oxygen atoms and one nitrogen atom of dimethylformamide and involves four fluoride ions.

  DOI：

  10.1134/s0036023611110246
• 作为产物：
  描述：

  gadolinium(III) oxide 、 sodium fluoride 、 N,N-二甲基甲酰胺 在 hydrochloric acid 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 [Gd(dimethylformamide-O)2(dimethylformamide-N)F4](1-)
  参考文献：
  名称：

  Composition of a mixed-ligand gadolinium(III) complex in fluoride-dimethylformamide electrolyte

  摘要：

  The gadolinium(III) complex formed in a fluoride-dimethylformamide (DMF) electrolyte was studied by linear-sweep voltammetry and IR spectroscopy. The composition of the mixed-ligand complex formed was found to correspond to the component ratios Gd: DMF: F = 1: 3: 4. It has been found that the coordination link in the complex is via two oxygen atoms and one nitrogen atom of dimethylformamide and involves four fluoride ions.

  DOI：

  10.1134/s0036023611110246