Cu(BIm)2Cl2*H2O | 193562-18-4

• 英文名称: Cu(BIm)2Cl2*H2O
• 英文别名: Cu(benzimidazole)2Cl2*H2O
• CAS: 193562-18-4
• 化学式: C₁₄H₁₂Cl₂CuN₄*H₂O
• 分子量: 388.743
• InChiKey: BQEPRZSWDDXPFL-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  Cu(BIm)2Cl2*H2O 以 neat (no solvent) 为溶剂， 生成 Cu(benzimidazole)2Cl2
  参考文献：
  名称：

  Effect of the condition of synthesis on the composition and structure of copper(II) complexes with benzimidazole

  摘要：

  The composition and structure of copper(II) benzimidazole complexes obtained by the reaction of CuCl2 with benzimidazole (BIm) were determined. At pH 4.5-5.5, depending on the reactant ratio, dimeric compounds with the composition Cu(BIm) 4Cl(2) center dot 2H(2)O and Cu(BIm) 2Cl(2) center dot H2O are formed. They are converted to monomers at about 200 degrees C. At pH > 8, irrespective of the reactant ratio, the polymer (Cu(OH)L)(n) is formed. The complexation of copper(II) with benzimidazole in water and aqueous dioxane was studied by potentiometry, and the stability constants of the complex compounds and their dependence on the solvent composition were determined.

  DOI：

  10.1134/s0036023610090159
• 作为产物：
  描述：

  苯并咪唑 、 copper(II) choride dihydrate 在 HCl 作用下， 以 乙醇 为溶剂， 生成 Cu(BIm)2Cl2*H2O
  参考文献：
  名称：

  Effect of the condition of synthesis on the composition and structure of copper(II) complexes with benzimidazole

  摘要：

  The composition and structure of copper(II) benzimidazole complexes obtained by the reaction of CuCl2 with benzimidazole (BIm) were determined. At pH 4.5-5.5, depending on the reactant ratio, dimeric compounds with the composition Cu(BIm) 4Cl(2) center dot 2H(2)O and Cu(BIm) 2Cl(2) center dot H2O are formed. They are converted to monomers at about 200 degrees C. At pH > 8, irrespective of the reactant ratio, the polymer (Cu(OH)L)(n) is formed. The complexation of copper(II) with benzimidazole in water and aqueous dioxane was studied by potentiometry, and the stability constants of the complex compounds and their dependence on the solvent composition were determined.

  DOI：

  10.1134/s0036023610090159