[Cd(2-pyridineformamide-3-piperidylthiosemicarbazone)Cl2 | 420087-50-9

• 英文名称: [Cd(2-pyridineformamide-3-piperidylthiosemicarbazone)Cl2
• CAS: 420087-50-9
• 化学式: C₁₂H₁₇CdCl₂N₅S
• 分子量: 446.682
• InChiKey: PUEYTSJMKKZARB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cd(2-pyridineformamide-3-piperidylthiosemicarbazone)Cl2 、 二甲基亚砜 以 二甲基亚砜 为溶剂， 生成 [Cd(2-pyridineformamide-3-piperidylthiosemicarbazone)Cl2*DMSO
  参考文献：
  名称：

  Coordination of ZnII, CdII, and HgII by 2-Pyridineformamide-3-piperidyl-thiosemicarbazone

  摘要：

  Sodium in dry methanol reduces 2-cyanopyridine in the presence of 3-piperidylthiosemicarbazide and produces 2-pyridineformamide-3-piperidylthiosemicarbazone, HAmpip. Complexes with zinc(II), cadmium(II), and mercury(II) have been prepared and characterized by elemental analyses and spectroscopic techniques. In addition, the crystal structures of [Zn(Ampip)(2)], [Zn(Ampip)(Oac)](2), [Cd(HAmpip)Cl-2].(CH3)(2)SO, [Cd(HAmpip)Br-2] (.) (CH3)(2)SO, [Cd(HAmpip)I-2].(CH3)(2)SO, [Cd(Ampip)(2)] and [Hg(HAmpip)Br-2].(CH3)(2)SO have been solved. Coordination of the anionic and neutral thiosemicarbazone ligand is via the pyridyl nitrogen, imine nitrogen and thiolato/thione sulfur atom, respectively. In [Zn(Ampip)(OAc)](2) one of the bridging acetato ligands has monodentate coordination and the other bridges in a bidentate manner. Cd-113 NMR studies were carried out on the [Cd(HAmpip)X-2] (X = Cl, Br or I) and [Cd(Ampip)(OAc)](2) complexes. The Cd-113 chemical shifts are affected by the halogen and range from 411 to 301 ppm, and the spectrum of [Cd(Ampip)(OAc)](2) shows two signals at 450 and 251 ppm. The Hg-199 NMR spectrum of [Hg(HAmpip)Cl-2] also is discussed.

  DOI：

  10.1002/1521-3749(200202)628:2<492::aid-zaac492>3.0.co;2-v
• 作为产物：
  描述：

  N'-(piperidine-1-carbonothioyl)picolinohydrazonamide 、 cadmium(II) chloride 以 乙醇 为溶剂， 以69.9%的产率得到[Cd(2-pyridineformamide-3-piperidylthiosemicarbazone)Cl2
  参考文献：
  名称：

  Coordination of ZnII, CdII, and HgII by 2-Pyridineformamide-3-piperidyl-thiosemicarbazone

  摘要：

  Sodium in dry methanol reduces 2-cyanopyridine in the presence of 3-piperidylthiosemicarbazide and produces 2-pyridineformamide-3-piperidylthiosemicarbazone, HAmpip. Complexes with zinc(II), cadmium(II), and mercury(II) have been prepared and characterized by elemental analyses and spectroscopic techniques. In addition, the crystal structures of [Zn(Ampip)(2)], [Zn(Ampip)(Oac)](2), [Cd(HAmpip)Cl-2].(CH3)(2)SO, [Cd(HAmpip)Br-2] (.) (CH3)(2)SO, [Cd(HAmpip)I-2].(CH3)(2)SO, [Cd(Ampip)(2)] and [Hg(HAmpip)Br-2].(CH3)(2)SO have been solved. Coordination of the anionic and neutral thiosemicarbazone ligand is via the pyridyl nitrogen, imine nitrogen and thiolato/thione sulfur atom, respectively. In [Zn(Ampip)(OAc)](2) one of the bridging acetato ligands has monodentate coordination and the other bridges in a bidentate manner. Cd-113 NMR studies were carried out on the [Cd(HAmpip)X-2] (X = Cl, Br or I) and [Cd(Ampip)(OAc)](2) complexes. The Cd-113 chemical shifts are affected by the halogen and range from 411 to 301 ppm, and the spectrum of [Cd(Ampip)(OAc)](2) shows two signals at 450 and 251 ppm. The Hg-199 NMR spectrum of [Hg(HAmpip)Cl-2] also is discussed.

  DOI：

  10.1002/1521-3749(200202)628:2<492::aid-zaac492>3.0.co;2-v