[1-butyl-3-methyl-1H-imidazolium][Ga2Cl7] | 1057290-14-8

• 英文名称: [1-butyl-3-methyl-1H-imidazolium][Ga2Cl7]
• 英文别名: [bmim](+)[Ga2Cl7](-)
• CAS: 1057290-14-8
• 化学式: C₈H₁₅N₂*Cl₇Ga₂
• 分子量: 526.838
• InChiKey: STBRKNOAOXVYAH-UHFFFAOYSA-G

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氯化镓 、 氯化(1-丁基-3-甲基咪唑) 生成 [1-butyl-3-methyl-1H-imidazolium][Ga2Cl7]
  参考文献：
  名称：

  Super acidic ionic liquids for arene carbonylation derived from dialkylimidazolium chlorides and MCl3 (M=Al, Ga, or In)

  摘要：

  Ionic liquids, formed by combining 1 mol of 1-butyl-3-methyl-1H-imidazolium chloride, bmim(+) -Cl-, with 2 mol of a Group IIIA metal chloride (Al, Ga, In), were examined for toluene carbonylation reactivity to determine the effect for changing the M(III) cation. These ionic liquids were characterized for Bronsted acidity indirectly by C-13 NMR of labeled acetone, CH3-*CO-CH3. These results were explained by a mechanism where the Bronsted acidity of the ionic liquid was influenced by the strength of the Lewis acid: M3+Cl3. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2007.07.044