[Fe3Au(μ4,η2-CC-t-Bu)(CO)9(PPh3)] | 406203-76-7

• 英文名称: [Fe3Au(μ4,η2-CC-t-Bu)(CO)9(PPh3)]
• 英文别名: [Fe3Au(μ3,η2-CC-t-Bu)(CO)9(PPh3)]
• CAS: 406203-76-7；406203-74-5
• 化学式: C₃₃H₂₄AuFe₃O₉P
• 分子量: 960.029
• InChiKey: DSLYSJAHOVIFMB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 [Fe3Au(μ4,η2-CC-t-Bu)(CO)9(PPh3)] 以 四氢呋喃 为溶剂， 生成 [(μ-H)Fe3(CO)9(CCtBu)]
  参考文献：
  名称：

  Fast and Reversible Intramolecular Cleavage of an Au−C Bond in the Spiked-Triangular Metal Complexes [Fe₃Au(μ₄,η²-C⋮C^tBu)(CO)₉(PR₃)] (R = Ph, ⁱPr)

  摘要：

  The C-S bond cleavage in the alkynethiolate ligand of the compound Li[Fe-3(mu(3)-SCdropC(t)Bu)(CO)(9)] (1a) takes place in its reaction with [AuClPR3] (R = Ph, Pr-i), affording the complexes [Fe3Au(mu(4),eta(2)-CdropC(t)Bu)(CO)(9)-(PR3)] (R = Ph (3a), Pr-i (3b)). The gold fragment displays an unexpected bonding mode, and a fast and reversible process of oxidative addition/reductive elimination of the Au-C bond has been observed in solution.

  DOI：

  10.1021/om010980b
• 作为产物：
  描述：

  三苯基膦氯金 、 Li[Fe3(μ3-SCC-t-Bu)(CO)9] 在 TlBF₄ 作用下， 以 四氢呋喃 为溶剂， 生成 [Fe3Au2(μ3-S)(CO)9(PPh3)2] 、 [Fe3Au(μ4,η2-CC-t-Bu)(CO)9(PPh3)]
  参考文献：
  名称：

  Fast and Reversible Intramolecular Cleavage of an Au−C Bond in the Spiked-Triangular Metal Complexes [Fe₃Au(μ₄,η²-C⋮C^tBu)(CO)₉(PR₃)] (R = Ph, ⁱPr)

  摘要：

  The C-S bond cleavage in the alkynethiolate ligand of the compound Li[Fe-3(mu(3)-SCdropC(t)Bu)(CO)(9)] (1a) takes place in its reaction with [AuClPR3] (R = Ph, Pr-i), affording the complexes [Fe3Au(mu(4),eta(2)-CdropC(t)Bu)(CO)(9)-(PR3)] (R = Ph (3a), Pr-i (3b)). The gold fragment displays an unexpected bonding mode, and a fast and reversible process of oxidative addition/reductive elimination of the Au-C bond has been observed in solution.

  DOI：

  10.1021/om010980b