[(Ti(acetylacetonato)2Cl)(Ti(η5-C5H5)2(Cl))(μ-O)] | 375395-32-7

• 英文名称: [(Ti(acetylacetonato)2Cl)(Ti(η5-C5H5)2(Cl))(μ-O)]
• CAS: 375395-32-7
• 化学式: C₂₀H₂₄Cl₂O₅Ti₂
• 分子量: 511.074
• InChiKey: NOKQVFAOBCRBMN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二氯二茂钛 、 乙酰丙酮 在 triethylamine 作用下， 以 乙腈 为溶剂， 以40%的产率得到[(Ti(acetylacetonato)2Cl)(Ti(η5-C5H5)2(Cl))(μ-O)]
  参考文献：
  名称：

  Synthesis and crystal structure of oxo-bridged binuclear titanium complex [{Ti(acac)2Cl}{TiCp2(Cl)}(μ-O)] and its catalytic reactions toward silation of aldehyde

  摘要：

  Reaction of [Cp2TiCl2] with two equivalents of 2,4-pentanedione in the presence of one equivalent of NEt3 in CH3CN at room temperature yielded oxo-bridged binuclear titanium complex [{Ti(acac)(2)Cl} {TiCP2(Cl)} (mu -O)], which was characterized crystallographically and spectroscopically. Reaction mixture of oxo-bridged binuclear titanium complex and 2 " BuLi catalytically activate the mixture of phenylsilane and aldehyde to yield O-silation products at room temperature. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01021-x