[Y(N-(3-tert-butyl-2-oxy)benzylidenepentafluorophenylamine)2(N(Si(CH3)3)2)] | 500556-59-2

• 英文名称: [Y(N-(3-tert-butyl-2-oxy)benzylidenepentafluorophenylamine)2(N(Si(CH3)3)2)]
• CAS: 500556-59-2
• 化学式: C₄₀H₄₄F₁₀N₃O₂Si₂Y
• 分子量: 933.869
• InChiKey: PNYFKWVGDVRCMX-GBHDXLSQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(trimethylsilyl)amide yttrium(III) 、 N-(3-tert-butyl-2-hydroxy)benzylidenepentafluorophenylamine 以 甲苯 为溶剂， 生成 [Y(N-(3-tert-butyl-2-oxy)benzylidenepentafluorophenylamine)3] 、 [Y(N-(3-tert-butyl-2-oxy)benzylidenepentafluorophenylamine)2(N(Si(CH3)3)2)]
  参考文献：
  名称：

  Synthesis, structure and catalytic activity of new iminophenolato complexes of scandium and yttrium

  摘要：

  The reaction of equimolar amounts of 2-(2,4,6-Me3C6H2N = CH)(6-Bu')C6H3OH (HL') with M(CH2SiMe3)(3)(THF)(3) (M = Sc or Y) under mild conditions gives M(CH2SiMe3)(2)(THF)(L-1). The trigonal-bipyramidal structure of these dialkyls was confirmed crystallographically for M = Sc. Whereas the scandium complex is stable in solution at room temperature, the yttrium derivative slowly disproportionates to give Y(L-1)(3) which is also accessible from Y(CH2SiMe3)(3)(THF)(3) and three HL'. The X-ray structure of Y(L)3 indicates a chiral tris-chelate complex. While the reaction of the related ligand (2-CyN = CH)(6-Bu')C6H3OH (HL2, CY = cyclohexyl) with Sc(CH2SiMe3)(3)(THF)(3) gives the expected dialkyl Sc(CH2SiMe3)(2)(THF)(L-2), the reaction with the yttrium analogue affords the six-coordinate monoalkyl product Y(CH2SiMe3)(THF)(L-2)(2). This product is stable in solution towards disproportionation. The reaction of Y[N(SiMe3)(2)](3) with (2-C6F5N = CH)(6-Bu')C6H3OH (HL3) affords Y{N(SiMe3)(2)}(L-3)(2) and Y(L-3)(3). Both complexes are seven-coordinate in the solid state due to Y...F co-ordination to the C6F5 substituents. The scandium alkyl complexes are efficient catalysts for the ring-opening polymerisation of F-caprolactone. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01657-1