(η(5)-C5H5)Co(Br)(S2C2(COOMe)2)(CH(COOMe)2) | 247103-47-5

• 英文名称: (η(5)-C5H5)Co(Br)(S2C2(COOMe)2)(CH(COOMe)2)
• CAS: 247103-47-5
• 化学式: C₁₆H₁₈BrCoO₈S₂
• 分子量: 541.343
• InChiKey: GPOGNIKLDUDRNQ-WTUPQPTJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (η(5)-cyclopentadienyl)(2-[(bis(methoxycarbonyl)methanido)thio-κC,κS]-1,2-bis(methoxycarbonyl)ethenethiolato-κS)cobalt(III) 、 氢溴酸 以 二氯甲烷 为溶剂， 生成 (η(5)-C5H5)Co(Br)(S2C2(COOMe)2)(CH(COOMe)2)
  参考文献：
  名称：

  Electrochemical Methods:  Analyses of Structures and Determination of Properties of the Cobaltadithiolene Derivatives [CpCoX(S₂C₂(COOMe)₂)(CHR¹R²)] (X = Cl, Br, and I)

  摘要：

  The electrochemical behavior of cobaltadithiolene derivatives [CpCoX(S2C2(COOMe)(2))((CHRR2)-R-1)] (X = Cl, Br, and I, (R-1, R-2) = (H, H), (H, COOEt), (COOMe, COOMe), and (H, SiMe3)) showed the easy elimination of halide, and the formation of an equilibrium system between these complexes and their corresponding cation complexes and eliminated halide. We report a methodology that proves the existence of this equilibrium in solutions together with their redox behavior according to the application and uses of electrochemical measurements.

  DOI：

  10.1021/om990181h