Me2Al(OC(=NC6H4Me)C((N-mesityl)N(CHCH)N(CHCH2N(t-Bu)C(=NC6H4Me)O))) | 1354047-46-3

• 英文名称: Me2Al(OC(=NC6H4Me)C((N-mesityl)N(CHCH)N(CHCH2N(t-Bu)C(=NC6H4Me)O)))
• CAS: 1354047-46-3
• 化学式: C₃₆H₄₆AlN₅O₂
• 分子量: 607.775
• InChiKey: PJRIQASWKOPXHL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-(2-(3-mesityl-2,3-dihydro-1H-imidazol-1-yl)ethyl)-2-methylpropan-2-amine 以 四氢呋喃 、 正庚烷 、 甲苯 为溶剂， 生成 Me2Al(OC(=NC6H4Me)C((N-mesityl)N(CHCH)N(CHCH2N(t-Bu)C(=NC6H4Me)O)))
  参考文献：
  名称：

  Subtle Reactivities of Boron and Aluminum Complexes with Amino-Linked N-Heterocyclic Carbene Ligation

  摘要：

  This paper describes the synthesis and characterization of trimethylaluminum (2a), dimethylaluminum (3a), and triphenylboron complexes (7) supported by functional amine-linked NHC ligands. The chemical reactivity studies with carbodiimide and isocyanate were preformed with 2a and 3a, illustrating the noninnocent nature in Al-carbene bonding. However, the boron-carbene interaction is quite robust against addition of these substrates even at higher temperature conditions. The subtle difference in chemical reactivity between aluminum and boron is attributed from the metal-carbene bond covalency. Development of the catalytic method for Suzuki-Miyaura coupling utilizing triphenylboron reagent supported by amino-NHC is also presented.

  DOI：

  10.1021/om200878e