(indoline)B(OH)3 | 1104738-21-7

• 英文名称: (indoline)B(OH)3
• CAS: 1104738-21-7
• 化学式: C₈H₁₂BNO₃
• 分子量: 180.999
• InChiKey: USPKCAYLOQLWOX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吲哚啉 在 catalyst: Pd/C 作用下， 以 四氢呋喃 、 水 为溶剂， 生成 (indole)B(OH)3 、 (indoline)B(OH)3
  参考文献：
  名称：

  Production of H₂ from Combined Endothermic and Exothermic Hydrogen Carriers

  摘要：

  One of the major limitations to the use of fuel cell systems in vehicular transportation is the lack of hydrogen storage systems that have the required hydrogen storage density and moderate enthalpy of dehydrogenation. Organic liquid H-2 carriers that release H-2 endothermically are easier to handle with existing infrastructure because they are liquids, but they have low storage densities and their endothermicity consumes energy in the vehicle. On the other hand, inorganic solid H-2 carriers that release H-2 exothermically have greater storage densities but are unpumpable solids. This paper explores combinations of an endothermic carrier and an exothermic carrier, where the exothermic carrier provides some or all of the necessary heat required for dehydrogenation to the endothermic system, and the endothermic carrier serves as a solvent for the exothermic carrier. The two carriers can be either physically mixed or actually bonded to each other. To test the latter strategy, a number of chemically bound N-heterocycle:BH3 adducts were synthesized and in turn tested for their ability to release H-2 by tandem hydrolysis of the BH3 moiety and dehydrogenation of the heterocycle. To test the strategy of physically mixing two carriers, the hydrolysis of a variety of amine-boranes (H3N:BH3, Me2HN:BH3, Et3N:BH3) and the catalytic dehydrogenation of indoline were carried out together.

  DOI：

  10.1021/ja806721s