2-[(N,N-dimethylaminomethyl)phenyl]diphenylstannylfluoride | 712351-41-2

• 英文名称: 2-[(N,N-dimethylaminomethyl)phenyl]diphenylstannylfluoride
• 英文别名: (2-(Me2NCH2C6H4)diphenyltin(IV) fluoride
• CAS: 712351-41-2
• 化学式: C₂₁H₂₂FNSn
• 分子量: 426.121
• InChiKey: HMSLRPSEUMWXLH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  2-[(N,N-dimethylaminomethyl)phenyl]diphenylstannylfluoride 、 以 四氢呋喃 为溶剂， 以44 %的产率得到
  参考文献：
  名称：

  C, N-螯合锑和铋络合物；氧化和氟化

  摘要：

  一组带有 2-{[(2,6-二异丙基苯基)亚氨基] 的有机锑 (III/V) 和有机铋 (V) 氟化物（即LSbF 2、LSbClF、LPh 2 SbF 2、LSbF 4和 LPh 2 BiF 2 ）甲基}苯基-作为C，N-螯合配体(L)已经使用L CN R 2 SnF制备(其中L CN  = 2-( N,N-二甲基氨基甲基)苯基)；R =  n -Bu 或 Ph) 和/或 XeF 2作为氟化剂。所有物种均通过元素分析和多核溶液 NMR 光谱学的组合进行表征。通过 sc-XRD 分析建立了所有复合物的固态结构。此外，还进行了理论计算以证实实验结果。还报道了LSbI 2的制备和结构表征。

  DOI：

  10.1016/j.jorganchem.2023.122644
• 作为产物：
  描述：

  potassium fluoride 、 [2-(N,N-二甲基氨基甲基)苯基]二苯基锡(IV)氯化物 以 乙醚 、 水 为溶剂， 以70%的产率得到2-[(N,N-dimethylaminomethyl)phenyl]diphenylstannylfluoride
  参考文献：
  名称：

  Monomeric Triorganotin(IV) Fluorides Containing a C,N-Chelating Ligand

  摘要：

  The set of four triorganotin(IV) fluorides of general formula {2-[(CH3)(2)NCH2]C6H4}R2SnF, where R is Me (5), n-Bu (6), t-Bu (7), and Ph (8), respectively, has been prepared and characterized using NMR and ESI-MS techniques. The structures of crystalline compounds 5 and 8 were determined using X-ray methods. All compounds are monomeric both in solution using different solvents and in the solid state. The tin central atom is five-coordinated with all carbon atoms in equatorial positions and fluorine and nitrogen, from the intramolecularly coordinated dimethylamino group, in the axial positions of the distorted trigonal bipyramid. The ability of compounds 6 and 8 to perform fluorination of organometallic chlorides was tested on titanocene dichloride. A quantitative yield Of CP2TiF2 was obtained.

  DOI：

  10.1021/om049912q

文献信息

• Hypercoordinated Organotin( <scp>IV</scp> ) Halides Containing 2‐(Me ₂ NCH ₂ )C ₆ H ₄ Groups: {2‐(Me ₂ NCH ₂ )C ₆ H ₄ } ₂ SnX ₂ (X = F, Cl, Br, I) and {2‐(Me ₂ NCH ₂ )C ₆ H ₄ }R ₂ SnX (R = Me, Ph; X = F, Cl, Br, I) and Their Solution Behaviour and Solid‐State, Hydrogen‐Bonding‐Based Supramolecular Architecture
  作者：Richard A. Varga、Adina Rotar、Markus Schürmann、Klaus Jurkschat、Cristian Silvestru

  DOI：10.1002/ejic.200501018

  日期：2006.4

  triorganotin(iv) chlorides [2-(Me 2 NCH 2 )C 6 H 4 } 2 SnCl 2 ] (la) and [2-(Me 2 NCH 2 )C 6 H 4 }-R 2 SnCl] [R = Me (2a), Ph (3a)] were prepared by treating SnCl 4 or R 2 SnCl 2 with [Li2-(Me2NCH2)C 6 H 4 }]. Halide-exchange reactions between the organotin(iv) chlorides and the appropriate potassium halides gave [2-(Me 2 NCH 2 )-C 6 H 4 } 2 SnX 2 ] [X = F (1b), I (1d)], [2-(Me 2 NCH 2 )C 6 H 4 }-Me 2

  超配位的二有机锡和三有机锡 (iv) 氯化物 [2-(Me 2 NCH 2 )C 6 H 4 } 2 SnCl 2 ] (la) 和 [2-(Me 2 NCH 2 )C 6 H 4 }-R 2 SnCl] [R = Me (2a), Ph (3a)] 通过用 [Li2-(Me2NCH2)C 6 H 4 }] 处理 SnCl 4 或 R 2 SnCl 2 来制备。有机锡 (iv) 氯化物和适当的卤化钾之间的卤化物交换反应得到 [2-(Me 2 NCH 2 )-C 6 H 4 } 2 SnX 2 ] [X = F (1b), I (1d)] , [2-(Me 2 NCH 2 )C 6 H 4 }-Me 2 SnX] [X = F (2b), Br (2c), I (2d)] 和 [2-(Me 2 NCH 2 ) -C 6 H 4 }Ph 2 SnX] [X = F (3b), I (3d)]。它们的溶液行为通过多核（