1-[3-(2,2,3,3,4,4,5,5,6,6-decafluoropiperidin-1-yl)-1,1,2,2,3,3-hexafluoropropyl]-2,2,3,3,4,4,5,5,6,6-decafluoropiperidine | 118878-15-2

• 英文名称: 1-[3-(2,2,3,3,4,4,5,5,6,6-decafluoropiperidin-1-yl)-1,1,2,2,3,3-hexafluoropropyl]-2,2,3,3,4,4,5,5,6,6-decafluoropiperidine
• CAS: 118878-15-2
• 化学式: C₁₃F₂₆N₂
• 分子量: 678.115
• InChiKey: QCWOSBISUSHJFF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.62
• 重原子数：
  41.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  N,N'-dipiperidylpropane 、 氢氟酸 以38%的产率得到
  参考文献：
  名称：

  NAYASHI, EIJI;ABE, TAKASHI;BABA, HAJINE;NAGASE, SHUNJI, CHEM. EXPRESS., 3,(1988) N, C. 191-194

  摘要：

  DOI：

文献信息

• On the electrochemical fluorination of derivatives of morpholine and piperidine
  作者：H. Meinert、R. Fackler、J. Mader、P. Reuter、W. Rohlke

  DOI：10.1016/s0022-1139(00)80306-1

  日期：1991.1

  Electrochemical fluorination (ECF) of alpha,omega-dimorpholino- and dipiperidino-alkanes of different chain length (n = 1-6) and of morpholinocyclohexene gave the perfluoro derivatives in yields up to 45%. By ring contractions, fragmentations and rearrangements several side products were obtained. Conclusions on the mechanism of ECF, based on a sterical model, were drawn.