[tetrakis(2-(2'-oxyphenyl)-2-oxazoline)dizinc] | 754189-47-4

• 英文名称: [tetrakis(2-(2'-oxyphenyl)-2-oxazoline)dizinc]
• CAS: 754189-47-4
• 化学式: C₃₆H₃₂N₄O₈Zn₂
• 分子量: 779.452
• InChiKey: VCJJKWNJMKKBCV-UHFFFAOYSA-J

计算性质

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• 重原子数：
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反应信息

• 作为产物：
  描述：

  锌 、 2-(4,5-二氢恶唑-2-基)苯酚 以 乙腈 为溶剂， 生成 [tetrakis(2-(2'-oxyphenyl)-2-oxazoline)dizinc]
  参考文献：
  名称：

  A simple oxazoline as fluorescent sensor for Zn 2+ in aqueous media

  摘要：

  2-(2 '-Hydroxyphenyl)-2-oxazoline is shown to be a highly-selective Zn2+ sensor with very simple molecular structure. It demonstrates an excellent fluorescence "turn-on" response to Zn2+ in aqueous medium even in the presence of other competing anions and detection capability for studying the distribution of Zn2+ in living human HeLa cells as a proof-of-concept. (C) 2016 Published by Elsevier B.V.

  DOI：

  10.1016/j.inoche.2016.03.025

文献信息

• A Blue Photoluminescent 2‐D Coordination Polymer Constructed by Dinuclear Zinc( <scp>II</scp> ) Subunits [Zn ₂ (oz) ₂ ] [Hoz = 2‐(2′‐Hydroxyphenyl)‐2‐oxazoline] and Dicyanamide
  作者：Jing Zhang、Song Gao、Chi‐Ming Che

  DOI：10.1002/ejic.200300719

  日期：2004.3

  the terminal oz group of the dinuclear [Zn(oz)2]2 complex (1) with dicyanamide [where Hoz = 2-(2′-Hydroxyphenyl)-2-oxazoline] results in the formation of a 2-D coordination polymer [Zn(oz)N(CN)2]n (2) based on [Zn2(oz)2] subunits. Both compounds exhibit strong blue photoluminescence but the coordination polymer 2 has greater thermal stability than the dinuclear complex 1. (© Wiley-VCH Verlag GmbH & Co

  双核 [Zn(oz)2]2 复合物 (1) 的末端 oz 基团替换为双氰胺 [其中 Hoz = 2-(2'-羟基苯基)-2-恶唑啉] 导致形成二维配位基于 [Zn2(oz)2] 亚基的聚合物 [Zn(oz)N(CN)2]n (2)。两种化合物都表现出强烈的蓝色光致发光，但配位聚合物 2 比双核配合物 1 具有更高的热稳定性。 (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)