| 309921-54-8

• CAS: 309921-54-8
• 化学式: C₂₆H₄₆F₃N₄Si₄Ta
• 分子量: 764.963
• InChiKey: QQIBEQDOUSWARE-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 二苯基镁 以 四氢呋喃 为溶剂， 以40%的产率得到
  参考文献：
  名称：

  Synthesis of tantalum fluoride complexes supported by bis(trimethylsilyl)benzamidinate ligands. X-ray structures of [PhC(NSiMe3)2]2TaF3 and [PhC(NSiMe3)2]2TaFPh2

  摘要：

  The reaction of [PhC(NSiMe3)(2)]Li(TMEDA) with TaF5 yields complex 1, [PhC(NSiMe3)(2)](2)TaF3, in 40% isolated yield. The solid-state structure of 1 shows a pentagonal, bipyramidal coordination geometry. Variable temperature F-19-NMR experiments reveal one singlet at an ambient temperature; decoalescence to two singlets (1:2 integration) is observed at - 20 degrees C. Complex 1 reacts with Me2Mg to produce [PhC(NSiMe3)(2)](2)TaMe3 (2). The reaction of 1 with Ph2Mg yields [PhC(NSiMe3)(2)](2)TaF2Ph (3) and [PhC(NSiMe3)(2)](2)TaFPh2 (4). Characterization of 4 by X-ray crystallography shows a ligand arrangement similar to that of 1. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00376-4
• 作为产物：
  描述：

  氟化钽(V) 、 (bis(trimethylsilyl)benzamidinato)Li(TMEDA) 以 甲苯 为溶剂， 以40%的产率得到
  参考文献：
  名称：

  Synthesis of tantalum fluoride complexes supported by bis(trimethylsilyl)benzamidinate ligands. X-ray structures of [PhC(NSiMe3)2]2TaF3 and [PhC(NSiMe3)2]2TaFPh2

  摘要：

  The reaction of [PhC(NSiMe3)(2)]Li(TMEDA) with TaF5 yields complex 1, [PhC(NSiMe3)(2)](2)TaF3, in 40% isolated yield. The solid-state structure of 1 shows a pentagonal, bipyramidal coordination geometry. Variable temperature F-19-NMR experiments reveal one singlet at an ambient temperature; decoalescence to two singlets (1:2 integration) is observed at - 20 degrees C. Complex 1 reacts with Me2Mg to produce [PhC(NSiMe3)(2)](2)TaMe3 (2). The reaction of 1 with Ph2Mg yields [PhC(NSiMe3)(2)](2)TaF2Ph (3) and [PhC(NSiMe3)(2)](2)TaFPh2 (4). Characterization of 4 by X-ray crystallography shows a ligand arrangement similar to that of 1. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00376-4