| 149796-64-5

• CAS: 149796-64-5
• 化学式: C₃₆H₅₆Cl₂N₂O₄Pt
• 分子量: 846.838
• InChiKey: YVAMAGWQZOIQGC-UHFFFAOYSA-L

物化性质

• 熔点：
  183-184 °C

反应信息

• 作为产物：
  描述：

  dichlorobis(dimethyl sulfoxide)platinum(II) 、 didodecyl 2,2′-bipyridine-4,4′-dicarboxylate 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Hydrogen Generation Using a Photoinduced Electron-transport System with a Molecular Catalyst in Vesicles

  摘要：

  我们构建了一个模仿自然光合作用的新型 H2 生成系统，在该系统中，电子通过光化学方式从囊泡内部水池中夹带的抗坏血酸迁移到溶解在外部水溶液中的 MV2+，并传递给嵌入囊泡膜中作为分子催化剂的铂(II)复合物。

  DOI：

  10.1246/cl.2011.345

文献信息

• Effect of Axial Interactions on the Formation of Mesophases: Comparison of the Phase Behavior of Dialkyl 2,2′-bipyridyl-4,4′-dicarboxylate Complexes of Pt(II), Pt(IV), and Pt(II)/Pt(IV) Molecular Alloys
  作者：Rachel J. Allenbaugh、Cynthia K. Schauer、Amanda Josey、James D. Martin、Denis V. Anokhin、Dimitri A. Ivanov

  DOI：10.1021/cm3018105

  日期：2012.12.11

  Crystal engineering through the use of metal-based interactions is relatively common, but this approach has not been widely used to develop highly ordered liquid-crystalline (LC) phases. Herein is presented a Pt(II)/Pt(IV) system with a highly ordered LC phase engineered to form through metal-based MX chain interactions of the type Pt(II)center dot center dot center dot Cl-Pt(IV). This LC material constitutes a molecular alloy in which a single mesophase is formed from two components, and is the first alloy to include a Pt(IV) component. The molecular alloy was characterized via differential scanning calorimetry (DSC), polarizing optical microscopy (POM), and variable-temperature X-ray diffraction (VT XRD). The alloy properties are contrasted with complimentary analyses of the individual components. The newly synthesized tetrachloro(dialkyl 4,4'-dicarboxylate-2,2'-bipyridyl)platinum(IV) complexes ((PtLCl4)-Cl-n, n is the number of carbons in the alkyl chain) are themselves liquid crystalline. Structural and thermal properties of the Pt(II) analogues are presented to provide context to the behaviors of the Pt(IV) species and the alloys. Single-crystal X-ray diffraction data is presented for (PtLCl2)-Cl-1 center dot CH2Cl2, (PtLCl2)-Cl-2, and (PtLCl2)-Cl-16-center dot 2CHCl(3). This study demonstrates the potential of mesophase ordering through carefully engineered metal-based interactions. The resulting alloy provides a phase for studying MX chain interactions outside of the solid state.