[(1,2,3,4,5-η)-6,9-dibenzyl-12-phenyl-9,12-dihydro(C60-I(h))[5,6]fulleren-1(6H)-yl](η2,η2-norbornadiene)rhodium(I) | 638132-44-2

• 英文名称: [(1,2,3,4,5-η)-6,9-dibenzyl-12-phenyl-9,12-dihydro(C60-I(h))[5,6]fulleren-1(6H)-yl](η2,η2-norbornadiene)rhodium(I)
• CAS: 638132-44-2
• 化学式: C₈₇H₂₇Rh
• 分子量: 1175.08
• InChiKey: BOEOAUAVLYSXNU-GHRLNIAVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  di-μ-chlorobis(norbornadiene)dirhodium(I) 、 1,4-dibenzyl-11-phenyl-1,4,11,12-tetrahydro[60]fullerene 、 6,9-dibenzyl-18-phenyl-1,6,9,18-tetrahydro(C60-Ih)[5,6]fullerene 在 (CH₃)3COK 作用下， 以 四氢呋喃 为溶剂， 以96%的产率得到[(1,2,3,4,5-η)-6,9-dibenzyl-12-phenyl-9,12-dihydro(C60-I(h))[5,6]fulleren-1(6H)-yl](η2,η2-norbornadiene)rhodium(I)
  参考文献：
  名称：

  Synthesis and catalytic activity of rhodium diene complexes bearing indenyl-type fullerene η5-ligand

  摘要：

  Rhodium eta(5)-complexes bearing an indenyl-type fullerene ligand, Rh[C-60(PhCH2)(2)Ph](cod) (2), Rh[C-60(PhCH2)(2)Ph](nbd) (3) and Rh(C70Ph3)(cod) (4), have been synthesized from the corresponding fullerene tri-adducts in 93-96% yields. X-ray crystallographic analysis of 4 indicated that the structure of 4 is similar to that of Rh(Ind)(cod). The rhodium complex 2 catalyzes alkyne trimerization reactions and hydroboration reactions. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00465-0