(CH2CHCCH3(OB(C6F5)3))Pt(P(phenyl)3)2 | 688008-00-6

• 英文名称: (CH2CHCCH3(OB(C6F5)3))Pt(P(phenyl)3)2
• CAS: 688008-00-6
• 化学式: C₅₈H₃₆BF₁₅OP₂Pt
• 分子量: 1301.74
• InChiKey: QRWSWQZIFCQPHQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙烯双(三苯基磷)铂 、 三(五氟苯基)硼烷 、 丁烯酮 以 四氢呋喃 为溶剂， 以54%的产率得到(CH2CHCCH3(OB(C6F5)3))Pt(P(phenyl)3)2
  参考文献：
  名称：

  Reaction of η2-enone and enal-platinum(0) complexes with Lewis acidic compounds

  摘要：

  Reaction of eta(2)-enone and enal-platinum(0) complexes Pt(CH2=CHCOR)(PPh3)(2) (R=H, Me) with Lewis acidic compounds BX3 (X = F, C6F5) afforded adducts formed by coordination of boron to oxygen of the carbonyl group. The X-ray structure determination of the adduct formed from B(C6F5)(3) and eta(2)-methylvinylketone complex showed no strong interaction between Pt and carbonyl carbon. In contrast to the inability of the palladium(0) eta(2)-enone complexes to form any Me3Al adduct, eta(2)-cyclohexe-noneplatinum(0) complex formed an isolable adduct with Me3Al, the structure of which was also confirmed by X-ray analysis. The NMR spectral parameters (Pt-C, Pt-P and P-P coupling constants) of these adducts were compared with those of the original eta(2)-enone or enal-platinum(0) complexes as well as the ordinary eta(3)-allylplatinum cation [Pt(PPh3)(2)(MeCHCHCH2)](+). (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.12.018