[RuCl(CO)(PMe3)3]2(μ-CH=CHCH2CH(OH)CH(OH)CH2CH=CH) | 478034-12-7

• 英文名称: [RuCl(CO)(PMe3)3]2(μ-CH=CHCH2CH(OH)CH(OH)CH2CH=CH)
• CAS: 478034-12-7
• 化学式: C₂₈H₆₆Cl₂O₄P₆Ru₂
• 分子量: 925.718
• InChiKey: NBNAHZVZRGZWSP-GHINQBGGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [RuCl(CO)(PMe3)3]2(μ-CH=CHCH2CH(OH)CH(OH)CH2CH=CH) 在 P₂O₅ 作用下， 以 not given 为溶剂， 生成 RuCl2(CO)(Me3P)3
  参考文献：
  名称：

  Synthesis and Characterization of Linear (CH)₈-Bridged Bimetallic Ruthenium Complexes

  摘要：

  Reactions of HCdropCCH(2)CH(OR)CH(OR)CH(2)CdropCH (R = H, MeSO2) with RuHCl(CO)(PPh3)(3) produced [RuCl(CO)(PPh3)(2)](2)(mu-CH=CHCH2CH(OR)CH(OR)CH2CH=CH), which on treatment with PMe3 gave [RuCl(CO)(PMe3)(3)](2)(mu-CH=CHCH2CH(OR)CH(OR)CH2CH=CH). Treatment of RuHCl(CO)(PPh3)(3) with (3E,5E)-HCdropCCH=CHCH=CHCdropCH produced [RuCl-(CO)(PPh3)(2)](2)(mu-CH=CHCH=CHCH=CHCH=CH). The later complex reacted with PMe3, 4-phenylpyridine (PhPy), and 2,6-(Ph2PCH2)(2)C5H3N (PMP) to give [RuCl(CO)(PMe3)(3)](2)(mu-CH=CHCH=CHCH=CHCH=CH), [RuCl(CO)(PhPY)(PPh3)(2)](2)(mu-CH=CHCH=CHCH=CHCH= CH), and [RuCl(CO)(PMP)](2)(mu-CH=CHCH=CHCH=CHCH=CH), respectively. The structures of [RuCl(CO)(PMe3)(3)](2)(mu-CH=CHCH2CH(OH)CH(OH)CH2CH=CH) and [RuCl(CO)(PMe3)(3)](2)-(mu-CH=CHCH=CHCH=CHCH=CH) have been confirmed by X-ray diffraction.

  DOI：

  10.1021/om020442e
• 作为产物：
  描述：

  [RuCl(CO)(PPh3)2]2(μ-CH=CHCH2CH(OH)CH(OH)CH2CH=CH) 、 三甲基膦 以 四氢呋喃 为溶剂， 以71%的产率得到[RuCl(CO)(PMe3)3]2(μ-CH=CHCH2CH(OH)CH(OH)CH2CH=CH)
  参考文献：
  名称：

  Synthesis and Characterization of Linear (CH)₈-Bridged Bimetallic Ruthenium Complexes

  摘要：

  Reactions of HCdropCCH(2)CH(OR)CH(OR)CH(2)CdropCH (R = H, MeSO2) with RuHCl(CO)(PPh3)(3) produced [RuCl(CO)(PPh3)(2)](2)(mu-CH=CHCH2CH(OR)CH(OR)CH2CH=CH), which on treatment with PMe3 gave [RuCl(CO)(PMe3)(3)](2)(mu-CH=CHCH2CH(OR)CH(OR)CH2CH=CH). Treatment of RuHCl(CO)(PPh3)(3) with (3E,5E)-HCdropCCH=CHCH=CHCdropCH produced [RuCl-(CO)(PPh3)(2)](2)(mu-CH=CHCH=CHCH=CHCH=CH). The later complex reacted with PMe3, 4-phenylpyridine (PhPy), and 2,6-(Ph2PCH2)(2)C5H3N (PMP) to give [RuCl(CO)(PMe3)(3)](2)(mu-CH=CHCH=CHCH=CHCH=CH), [RuCl(CO)(PhPY)(PPh3)(2)](2)(mu-CH=CHCH=CHCH=CHCH= CH), and [RuCl(CO)(PMP)](2)(mu-CH=CHCH=CHCH=CHCH=CH), respectively. The structures of [RuCl(CO)(PMe3)(3)](2)(mu-CH=CHCH2CH(OH)CH(OH)CH2CH=CH) and [RuCl(CO)(PMe3)(3)](2)-(mu-CH=CHCH=CHCH=CHCH=CH) have been confirmed by X-ray diffraction.

  DOI：

  10.1021/om020442e