H3Ru3(μ3-methoxymethylidyne)(carbonyl)9 | 71562-47-5

• 英文名称: H3Ru3(μ3-methoxymethylidyne)(carbonyl)9
• CAS: 71562-47-5
• 化学式: C₁₁H₆O₁₀Ru₃
• 分子量: 601.373
• InChiKey: QNWXHCFQYXEAHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  H3Ru3(μ3-methoxymethylidyne)(carbonyl)9 在 一氧化碳 作用下， 以 癸烷 为溶剂， 生成 HRu3(CO)10(μ-COCH3)
  参考文献：
  名称：

  Kinetics and mechanism of oxidative addition and reductive elimination of hydrogen on triruthenium clusters

  摘要：

  DOI：

  10.1021/ja00353a022
• 作为产物：
  描述：

  HRu3(CO)10(μ-COCH3) 在 氢气 作用下， 以 正己烷 为溶剂， 以93%的产率得到H3Ru3(μ3-methoxymethylidyne)(carbonyl)9
  参考文献：
  名称：

  含桥接碳炔配体的三重铁三金属簇的氢化。三桥联卡宾的还原裂解

  摘要：

  DOI：

  10.1021/om00074a003

文献信息

• Replacement of hydrido-ligands in [Ru₃(µ-H)₃(µ-H)₃(µ₃-COMe)(CO)₉] and [Ru₄(µ-H)₄(CO)₁₂] by triphenylphosphinegold groups: X-ray crystal structures of [AuRu₃(µ-H)₂(µ-COMe)(CO)₉(PPh₃)], [Au₃Ru₃(µ-COMe)(CO)₉(PPh₃)₃], and [Au₃Ru₄(µ-H)(CO)₁₂(PPh₃)₃]
  作者：Lawrence W. Bateman、Michael Green、Judith A. K. Howard、Kevin A. Mead、Rona M. Mills、Ian D. Salter、F. Gordon A. Stone、Peter Woodward

  DOI：10.1039/c39820000773

  日期：——

  The compounds [Ru3(µ-H)3-COMe)(CO)9 and [Ru4(µ-H)4(CO)12] react with [AuMe(PPh3)] to give gold–ruthenium cluster compounds, and the structures of [AuRu3(µ-H)2(µ3-COMe)(CO)9(PPh3)], [Au3Ru3(µ3-COMe)(CO)9(PPh3)3], and [Au3Ru4(µ-H)(CO)12(PPh3)3] have been established by single-cryst X-ray diffraction studies.

  化合物[Ru3(µ-H)3-COMe)(CO)9和[Ru4(µ-H)4(CO)12]与[AuMe(PPh3)]反应生成金钌簇化合物，[AuRu3(µ-H)2(µ3-COMe)(CO)9(PPh3)]的结构、通过单晶 X 射线衍射研究确定了[Au3Ru3(µ3-COMe)(CO)9(PPh3)3]和[Au3Ru4(µ-H)(CO)12(PPh3)3]的结构。
• Parfitt, Derrick S.; Jordan, Jeffrey D.; Keister, Jerome B., Organometallics, 1992, vol. 11, # 12, p. 4009 - 4015
  作者：Parfitt, Derrick S.、Jordan, Jeffrey D.、Keister, Jerome B.

  DOI：——

  日期：——
• Abdul Rahman, Zuraidah; Beanan, Lawrence R.; Bavaro, Lynn M., Journal of Organometallic Chemistry, 1984, vol. 263, p. 75 - 92
  作者：Abdul Rahman, Zuraidah、Beanan, Lawrence R.、Bavaro, Lynn M.、Modi, Sandeep P.、Keister, Jerome B.、Churchill, Melvyn Rowen

  DOI：——

  日期：——
• Methylidyne–diyne coupling reactions onto a triruthenium cluster core
  作者：Javier A Cabeza、Iván da Silva、Ignacio del Rı́o、Santiago Garcı́a-Granda、Vı́ctor Riera

  DOI：10.1016/s0020-1693(02)01444-5

  日期：2003.4

  Treatment of the methoxymethylidyne-bridged triruthenium cluster [Ru-3(mu-H)(mu-COMe)(CO)(10)] (1) with the symmetric diynes RCdropCCdropCR (R = Me, Ph, CH2OPh) led to separable mixtures of two regioisomers, [Ru-3(mu-H)(mu(3)-eta(3)-MeOCCR=CC=CR)(CO)(9)] and [Ru-3(mu-H)(mu(3)-eta(3)-MeOCC(CdropCR)=CR)(CO)(9)]. These products arise from the insertion of one of the alkyne moieties of the corresponding diyne into a Ru-C bond of the methylidyne ligand. In all cases, the second alkyne functionality remains uncoordinated. In contrast, the reactions of the trihydride cluster [Ru-3(mu-H)(3)(mu(3)-COMe)(CO)(9)] (2) with diphenylbutadiyne led to a mixture of regioisomers in which one alkyne group of the original diyne has inserted into a Ru-C bond of the methylidyne ligand while the remaining triple bond has been hydrogenated to a double bond. The X-ray structures of the two regioisomers formed in the reaction of 1 with 2,4-hexadiyne are reported. (C) 2002 Elsevier Science B.V. All rights reserved.
• Keister, Jerome B.; Onyeso, Christian C. O., Organometallics, 1988, vol. 7, # 11, p. 2364 - 2372
  作者：Keister, Jerome B.、Onyeso, Christian C. O.

  DOI：——

  日期：——