[(η5-1,3-(tert-butyl)2C5H3)Co(1,2-dicarba-closo-dodecarborane-1,2-diselenolato)] | 848891-16-7

• 英文名称: [(η5-1,3-(tert-butyl)2C5H3)Co(1,2-dicarba-closo-dodecarborane-1,2-diselenolato)]
• 英文别名: (1,3-di-t-butylcyclopentadienyl)Co(1,2-dicarba-closo-dodecaborane-1,2-diselenolate)
• CAS: 848891-16-7
• 化学式: C₁₅H₃₁B₁₀CoSe₂
• 分子量: 536.434
• InChiKey: QTWGSHILJYYGFS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [W(CO)3(py)3] 、 [(η5-1,3-(tert-butyl)2C5H3)Co(1,2-dicarba-closo-dodecarborane-1,2-diselenolato)] 在 BF₃*OEt₂ 作用下， 以 乙醚 为溶剂， 以40%的产率得到(1,3-di-t-butylcyclopentadienyl)CoW(CO)2[1,2-dicarba-closo-dodecaborane-1,2-diselenolate]2
  参考文献：
  名称：

  Hetero-nuclear Co–W complex CpttCoW(CO)2[Se2C2(B10H10)]2 from 16-electron half-sandwich complex CpttCo[Se2C2(B10H10)]

  摘要：

  The 16-electron half-sandwich cobalt complex Cp"Co[Se2C2(B10H10)] (Cp" = eta(5)-1,3-Bu2C5H3) (3) has been synthesized by the reaction of [(THF)(3)LiSe,C2B10H10Li(THF)](2) (2) with Cp"Co(CO)I-2 (1). The hetero-binuclear complex Cp"CoW(CO)(2) [Se2C2(B10H10)](2) (4) was obtained from the reaction of 3 with W(CO)(3)(py)(3) in the presence of BF3 (.) Et2O. The molecular structures of 3 and 4 have been determined by X-ray crystallographic study. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.09.005
• 作为产物：
  描述：

  [(THF)3Li(1,2-dicarba-closo-dodecaborane-1,2-diselenolate)Li(THF)]2 、 (1,3-di-t-butylcyclopentadienyl)Co(CO)I2 以 四氢呋喃 、 乙醚 为溶剂， 以66%的产率得到[(η5-1,3-(tert-butyl)2C5H3)Co(1,2-dicarba-closo-dodecarborane-1,2-diselenolato)]
  参考文献：
  名称：

  Hetero-nuclear Co–W complex CpttCoW(CO)2[Se2C2(B10H10)]2 from 16-electron half-sandwich complex CpttCo[Se2C2(B10H10)]

  摘要：

  The 16-electron half-sandwich cobalt complex Cp"Co[Se2C2(B10H10)] (Cp" = eta(5)-1,3-Bu2C5H3) (3) has been synthesized by the reaction of [(THF)(3)LiSe,C2B10H10Li(THF)](2) (2) with Cp"Co(CO)I-2 (1). The hetero-binuclear complex Cp"CoW(CO)(2) [Se2C2(B10H10)](2) (4) was obtained from the reaction of 3 with W(CO)(3)(py)(3) in the presence of BF3 (.) Et2O. The molecular structures of 3 and 4 have been determined by X-ray crystallographic study. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.09.005

文献信息

• Synthesis and structure of heterometallic complexes (RhFe, CoFe) containing bridging 1,2-dicarba-closo-dodecarborane-1,2-dichalcogenolato ligands
  作者：Shuyi Cai、Xiu-Feng Hou、Yin-Qiang Chen、Guo-Xin Jin

  DOI：10.1039/b607195c

  日期：——

  The prototype hetero-binuclear complexes containing metal-metal bonds, CpRh[E2C2(B10H10)]}[Fe(CO)3] (Cp = Cp* = eta 5-Me5C5, E = S(5a), Se(5b); Cp = Cp = eta 5-1,3-tBu2C5H3, E = S(6a), Se(6b)) and CpCo[E2C2(B10H10)]}[Fe(CO)3] (Cp = Cp* = eta 5-Me5C5, E = S(7a), Se(7b); Cp = Cp = eta 5-C5H5, E = S(8a), Se(8b)) were obtained from the reactions of 16-electron complexes CpRh[E2C2(B10H10)] (Cp = Cp*, E

  包含金属-金属键CpRh [E2C2（B10H10）]} [Fe（CO）3]的原型异双核络合物（Cp = Cp * = eta 5-Me5C5，E = S（5a），Se（5b） ; Cp = Cp = eta 5-1,3-tBu2C5H3，E = S（6a），Se（6b））和CpCo [E2C2（B10H10）]} [Fe（CO）3]（Cp = Cp * = eta 5-Me5C5，E = S（7a），Se（7b）; Cp = Cp = eta 5-C5H5，E = S（8a），Se（8b））由16电子配合物CpRh [E2C2 （B10H10）]（Cp = Cp *，E = S（1a），Se（1b）； Cp = Cp，E = S（2a），Se（2b）），CpCo [E2C2（B10H10）]（Cp = Cp *，E = S（3a），Se（3b）; Cp = Cp，E = S（4a），