[Ag(1,2-bis(thiophen-2-ylmethylene)hydrazine)2]PF6 | 1020688-82-7

• 英文名称: [Ag(1,2-bis(thiophen-2-ylmethylene)hydrazine)2]PF6
• CAS: 1020688-82-7
• 化学式: C₂₀H₁₆AgN₄S₄*F₆P
• 分子量: 693.47
• InChiKey: LPWWAKGVCBPRJA-HSBSEAGTSA-N

反应信息

• 作为产物：
  描述：

  六氟磷酸银 、 (1E,2E)-1,2-bis(thiophen-2-ylmethylene)hydrazine 以 甲醇 、 二氯甲烷 为溶剂， 以64%的产率得到[Ag(1,2-bis(thiophen-2-ylmethylene)hydrazine)2]PF6
  参考文献：
  名称：

  Silver coordination polymers and networks based on O- or S-heterocyclic linking ligands: [AgL12](PF6), [Ag2L23](PF6)2, [Ag2L23](ClO4)2, [Ag2L22](BF4)2, and [Ag2L2(NO3)2] (L1=1,2-bis(thiophen-2-ylmethylene)hydrazine; L2=1,2-bis(furan-2-ylmethylene)hydrazine)

  摘要：

  Five silver compounds [AgL21](PF6) (1), [Ag2L32 PF6)(2) (2), [Ag2L32)(ClO4)(2) (3), [Ag2L22](BF4)(2) (4), and [Ag2L2(NO3)(2)](5) were prepared by layer diffusion (dichloromethane-methanol), where L-1 is 1,2-bis(thiophen-2-ylmethylene)hydrazine and L-2 is 1,2-bis(furan-2-ylmethylene)hydrazine. Compound 1 is a discrete compound. Whereas compounds 2 and 3 form 2D networks by van der Waals contacts, compounds 4 and 5 are a 1D and a 2D coordination polymer, respectively, formed by covalent bonds. In particular, compound 5 exhibited blue-green photoluminescence at room temperature in the solid state. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.12.018