[Mn(η(5)-C5Ph5)(CO)3] | 892501-05-2

• 英文名称: [Mn(η(5)-C5Ph5)(CO)3]
• CAS: 892501-05-2
• 化学式: C₃₈H₂₅MnO₃
• 分子量: 584.553
• InChiKey: YMZORYMMCQYBDN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Mn(η(5)-C5Ph5)(CO)3] 、 二甲基苯基磷 在 trimethylamine oxide 作用下， 以 四氢呋喃 为溶剂， 以81%的产率得到[Mn(η(5)-C5Ph5)(CO)2(PMe2Ph)]
  参考文献：
  名称：

  Manganese complexes of the pentaphenylcyclopentadienyl ligand

  摘要：

  The preparation and characterisation of [Mn(eta(5)-C5Ph5)(CO)(3)] (1), [Mn(eta(5)-C5Ph5)(CO)(2)(PMe2Ph)] (2), and [Mn(eta(5)-C-5(p-tol)(5))(CO)(3)] (3) are described; these complexes are the first reported fully characterised C5Ar5- derivatives of Group 7. Compounds (1) and (3) are reversibly oxidised at +0.98 and +0.89 V, respectively (versus Fc(+/0)), significantly more positive than the oxidation of the analogous [Mn(eta(5)-C5H5)(CO)(3)]. Single crystal X-ray diffraction studies of (1) and (2) (refined to R-1(F) 0.0967, wR(2)(F-2) 0.2971 and R-1(F) 0.0472, wR(2)(F-2) 0.1356, respectively) are also reported. (C) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.08.055
• 作为产物：
  描述：

  5-溴-1,2,3,4,5-五苯基-1,3-环戊二烯 、 MnBr(MeCN)2(CO)3 以 四氢呋喃 为溶剂， 以59%的产率得到[Mn(η(5)-C5Ph5)(CO)3]
  参考文献：
  名称：

  Manganese complexes of the pentaphenylcyclopentadienyl ligand

  摘要：

  The preparation and characterisation of [Mn(eta(5)-C5Ph5)(CO)(3)] (1), [Mn(eta(5)-C5Ph5)(CO)(2)(PMe2Ph)] (2), and [Mn(eta(5)-C-5(p-tol)(5))(CO)(3)] (3) are described; these complexes are the first reported fully characterised C5Ar5- derivatives of Group 7. Compounds (1) and (3) are reversibly oxidised at +0.98 and +0.89 V, respectively (versus Fc(+/0)), significantly more positive than the oxidation of the analogous [Mn(eta(5)-C5H5)(CO)(3)]. Single crystal X-ray diffraction studies of (1) and (2) (refined to R-1(F) 0.0967, wR(2)(F-2) 0.2971 and R-1(F) 0.0472, wR(2)(F-2) 0.1356, respectively) are also reported. (C) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.08.055