Cp*Ir(CO)(Br)2 | 1421745-36-9

• 英文名称: Cp*Ir(CO)(Br)2
• 英文别名: Cp*Ir(CO)(Br)₂
• CAS: 1421745-36-9
• 化学式: C₁₁H₁₅Br₂IrO
• 分子量: 515.268
• InChiKey: KAUWNLNBNAZGOQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  一氧化碳 、 [Cp*IrBr₂]₂ 以 二氯甲烷 为溶剂， 反应 2.0h， 生成 Cp*Ir(CO)(Br)2
  参考文献：
  名称：

  The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water

  摘要：

  The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any beta-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.11.030

文献信息

• The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne: Formation of a η3-tetraenyl transition metal complex
  作者：Kar Hang Garvin Mak、Wai Yip Fan、Venugopal Shanmugham Sridevi、Weng Kee Leong

  DOI：10.1016/j.jorganchem.2013.04.037

  日期：2013.9

  Reaction of the dimeric species [Cp*IrCl2](2) with 2-methyl-1-butene-3-yne results in C-C bond formation between two alkyne molecules and their coordination to an iridium center to form a complex containing a eta(3)-tetraenyl ligand. The reaction pathway has been studied experimentally and computationally. (C) 2013 Elsevier B. V. All rights reserved.