[(Cu(6,6'-dihydroxy-2,2'-[ethylenediyldioxybis(nitrilomethylidyne)]diphenol(3-))(CH3CH2CH2CH2OH))2Cu] | 1173289-74-1

• 英文名称: [(Cu(6,6'-dihydroxy-2,2'-[ethylenediyldioxybis(nitrilomethylidyne)]diphenol(3-))(CH3CH2CH2CH2OH))2Cu]
• CAS: 1173289-74-1
• 化学式: C₄₀H₄₆Cu₃N₄O₁₄
• 分子量: 997.462
• InChiKey: FVOFJYKOYUEGIZ-UWLRPYKMSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  6,6'-dihydroxy-2,2'-[ethylenediyldioxybis(nitrilomethylidyne)]diphenol 、 copper(II) acetate monohydrate 、 正丁醇 以 正丁醇 为溶剂， 以28.9%的产率得到[(Cu(6,6'-dihydroxy-2,2'-[ethylenediyldioxybis(nitrilomethylidyne)]diphenol(3-))(CH3CH2CH2CH2OH))2Cu]
  参考文献：
  名称：

  Synthesis, structural characterization and solvent effect of copper(II) complexes with a variational multidentate Salen-type ligand with bisoxime groups

  摘要：

  Four new solvent-induced Cu(II) complexes with the chemical formulae [{Cu(HL)(CH(3)OH)}(2)Cu] center dot CH(3)OH (1), [{(Cu(HL))(2)(CH(3)CH(2)OH)(2)}Cu] (2), [{CuL(H(2)O)}(2)Cu(2)] center dot 2CH(3)CH(2)CH(2)OH (3) and [{(Cu(HL))(2)(CH(3)CH(2)CH(2)CH(2)OH)(2)} Cu] (4), where H(4)L = 6,6'-dihydroxy-2,2'-[ethylenediyldioxybis(nitrilomethylidyne)]diphenol, have been synthesized and characterized by elemental analyses, (1)H NMR, FT-IR, UV-Vis spectra, TGDTA, molar conductances and X-ray crystallography. Complexes 1, 2 and 4 have an elongated square-pyramidal geometry with an unusually long bond from the penta-coordinated Cu(II) centres to the oxygen atoms of the apically coordinated solvent (methanol, ethanol or n-butanol) molecules for the terminal Cu(II) ions, and a square planar geometry distorted tetrahedrally for the central Cu(II) ion. In complex 3, the terminal Cu(II) ions have trigonal bipyramidal coordination geometries constituted by equatorial O(2)N donor sites, with one oxygen atom from one of the coordinated water molecules and one nitrogen atom from a completely deprotonated L(4-) ligand unit in the axial positions, and the central Cu(II) ions are in slightly tetrahedrally distorted square planar geometries constituted by four phenoxo oxygen donors from two completely deprotonated L4(-) ligand units, and these form a tetrametal Cu-O-Cu-O-Cu-O-Cu-O eight-membered ring. These four complexes exhibit strong hydrogen bonding interactions in the solid state. Moreover, co-crystallizing n-propanol molecules link two other adjacent complex molecules into a self-assembled infinite 2D supramolecular structure via the intermolecular hydrogen bonds in complex 3. (C) 2009 Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2009.03.017