(N-[4-(acetylamino)-η6-phenyl]acetamide)[1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)-κ2P,P']hydridoruthenium(II)trifluoromethanesulfonate | 528572-74-9

• 英文名称: (N-[4-(acetylamino)-η6-phenyl]acetamide)[1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)-κ2P,P']hydridoruthenium(II)trifluoromethanesulfonate
• CAS: 528572-74-9
• 化学式: CF₃O₃S*C₅₄H₄₅N₂O₂P₂Ru
• 分子量: 1066.05
• InChiKey: JXGBAGUIMHQDDA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Ru(OAc)2((S)-BINAP) 、 三氟甲磺酸 、 N,N'-二乙酰-1,4-苯二胺 以 异丙醇 为溶剂， 以74%的产率得到(N-[4-(acetylamino)-η6-phenyl]acetamide)[1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)-κ2P,P']hydridoruthenium(II)trifluoromethanesulfonate
  参考文献：
  名称：

  A Facile Synthesis of a Wide Variety of Cationic Ruthenium Hydrido-Arene Complexes of binap (=1,1′-Binaphthalene-2,2′-diylbis(diphenylphosphane)) and MeObiphep (=6,6′-Dimethoxybiphenyl-2,2′-diylbis(diphenylphosphane))

  摘要：

  A straightforward high-yield synthetic route to the cationic hydrido-arene complexes [RuH(eta(6)-arene)(binap or MeO-biphep)](CF3SO3), with a variety of arenes containing both donor and acceptor substituents, is described. C-13-NMR Data for these complexes are reported. Several of these Ru-complexes have been used as transfer-hydrogenation catalysts in the reduction of acetophenone.

  DOI：

  10.1002/1522-2675(200211)85:11<3937::aid-hlca3937>3.0.co;2-x