hydroxy(oxo)molybdenum(VI) tricyclohexylphosphonium bromide | 164669-66-3

• 英文名称: hydroxy(oxo)molybdenum(VI) tricyclohexylphosphonium bromide
• CAS: 164669-66-3
• 化学式: Br₄H₂MoO₂*C₁₈H₃₄P
• 分子量: 731.012
• InChiKey: SDRBZBDMKCRAFI-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  trans-{molybdenum(0)(carbonyl)4(P(cyclohexyl)3)2} 在 H₂O 、 air 作用下， 以 二氯甲烷 、 1,2-二氯乙烷 为溶剂， 以0-30的产率得到
  参考文献：
  名称：

  Bromination of molybdenum carbonyls revisited: oxo complexes and routes to new materials chemistry

  摘要：

  The use of in situ [{MoBr(mu-Br)(CO)(4)}(2)] led to considerably improved preparations of [MoBr2(CO)(3)(PPh(3))(2)] for which the rate of decarbonylation to [MoBr2(CO)(2)(PPh(3))(2)] is greatly increased by refluxing under reduced pressure (15-20 mmHg). Attempts to prepare [MoBr2- (CO)(2){P(C6H11)(3)}(2)] by Br-2 addition to cis- or trans-[Mo(CO)(4){P(C6H11)(3)}(2)] led to [HP(C6H11)(3)][Mo-(=0)Br(4)L] [L = OP(C6H11)(3) or H2O]. The OP(C6H11)(3) complex maybe used as a catalyst for the epoxidation of cyclohexene or for the addition of singlet oxygen to alpha-terpinene (1-isopropyl-4-methylcyclohexa-1, 3-diene). The species [HP(C6H11)(3)] [Mo(=0)Br-4{OP(C6H11)(3)}] was adsorbed onto sodium montmorillonite in a new type of reaction for sodium montmorillonite involving multiple abstractions of NaBr from the complex anion. In solution [HP(C6H11)(3)][Mo(=0)Br-4{OP(C6H11)(3)}] also decomposes to crystalline [Mo(=0)(2)Br-2{OP(C6H11)(3)}(2)] which is monoclinic, space group C2/c [a = 27.15(5), b = 8.486(8), c = 18.49(2) Angstrom, beta = 110.94(7)degrees].

  DOI：

  10.1039/dt9950001489