[Hg(abt)2Cl(SCN)] | 1333004-97-9

• 英文名称: [Hg(abt)2Cl(SCN)]
• 英文别名: [Hg(2-aminobenzothiazole)2Cl(SCN)]
• CAS: 1333004-97-9
• 化学式: C₁₅H₁₂ClHgN₅S₃
• 分子量: 594.535
• InChiKey: ZVAHJWPWJHINQU-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  硫氰酸铵 、 2-氨基苯并噻唑 、 [HgCl2(2-aminobenzothiazole)]_n 以 乙醇 、 水 为溶剂， 以40%的产率得到[Hg(abt)2Cl(SCN)]
  参考文献：
  名称：

  Three 2-Aminobenzothiazole-Based Mercury Complexes Tuned by Competitive Coordination Between the Coligands: Synthesis, Structures, and Fluorescent Properties

  摘要：

  Three novel Hg-II complexes, [Hg(abt)Cl-2](n) (1), [Hg(abt)(2) (SCN)Cl] (2), and [Hg-2(abt)(2)(SCN)(4)] (3), were obtained by reaction of HgCl2 and 2-aminobenzothiazole (abt) in the absence or presence of NH4SCN. As a significant result from the step-wise competitive coordination between SCN- and halide anions, the three complexes exhibit a polymeric one-dimensional (1D) array, discrete mononuclear entity, and centrosymmetric binuclear structure, which are further assembled into three-dimensional (3D) supramolecular networks by hydrogen bonding and pi-pi stacking interactions. Additionally, the three complexes display similar thermal stability and luminescent emissions, which essentially depend on the properties of abt core ligand.

  DOI：

  10.1080/15533174.2011.591305