2-tert-butyl-6-(N-ferrocenylaldimino)phenol | 878660-80-1

• 英文名称: 2-tert-butyl-6-(N-ferrocenylaldimino)phenol
• 英文别名: (FcPI)H
• CAS: 878660-80-1
• 化学式: C₂₁H₂₃FeNO
• 分子量: 361.267
• InChiKey: BEUTUJOGCOIGHR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2-tert-butyl-6-(N-ferrocenylaldimino)phenol 、 氯化锆(IV) 在 NaH 作用下， 以 四氢呋喃 为溶剂， 以42%的产率得到(FcPI)2ZrCl2
  参考文献：
  名称：

  Synthesis and structures of ferrocenyl-substituted salicylaldiminato complexes of magnesium, titanium and zirconium

  摘要：

  N-ferrocenyl salicylaldimine (FcPI)H, readily accessible from aminoferrocene and salicylaldehyde, reacts with dibutylmagnesium in THF to afford a red crystalline (FcPI)(2)Mg(THF)(2) (2). The reactions of the Li(FcPI) with CpTiCl3 gave CpTiCl2(FcPi) center dot CH2Cl2 (4), whereas with CpZrCl3 center dot DME a mixture of three products is formed: CpZrCl(FcPI)(2) (5), CpZrCl2(FcPi) (6), and (FcPI)(2)ZrCl2 center dot CH2Cl2 (3 center dot CH2O2). The crystal structures of compounds 2-6 are reported. Typically, the N-O chelates are oriented such that 0 donors are mutually trans, while N donors prefer to be trans to Cl ligands. The redox potentials of these complexes are very similar to ferrocene. On activation with methylaluminoxane, the Ti complex 4 shows moderate activity for ethylene polymerisation, while (FCPI)(2)ZrCl2 is highly active for the oligomerisation of ethylene, to give products with average degrees of polymerisation of 12-16. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.07.012
• 作为产物：
  描述：

  aminoferrocene 、 3-叔丁基-2-羟基苯甲醛 在 4Å molecular sieves 作用下， 以 乙醇 为溶剂， 以65%的产率得到2-tert-butyl-6-(N-ferrocenylaldimino)phenol
  参考文献：
  名称：

  Synthesis and structures of ferrocenyl-substituted salicylaldiminato complexes of magnesium, titanium and zirconium

  摘要：

  N-ferrocenyl salicylaldimine (FcPI)H, readily accessible from aminoferrocene and salicylaldehyde, reacts with dibutylmagnesium in THF to afford a red crystalline (FcPI)(2)Mg(THF)(2) (2). The reactions of the Li(FcPI) with CpTiCl3 gave CpTiCl2(FcPi) center dot CH2Cl2 (4), whereas with CpZrCl3 center dot DME a mixture of three products is formed: CpZrCl(FcPI)(2) (5), CpZrCl2(FcPi) (6), and (FcPI)(2)ZrCl2 center dot CH2Cl2 (3 center dot CH2O2). The crystal structures of compounds 2-6 are reported. Typically, the N-O chelates are oriented such that 0 donors are mutually trans, while N donors prefer to be trans to Cl ligands. The redox potentials of these complexes are very similar to ferrocene. On activation with methylaluminoxane, the Ti complex 4 shows moderate activity for ethylene polymerisation, while (FCPI)(2)ZrCl2 is highly active for the oligomerisation of ethylene, to give products with average degrees of polymerisation of 12-16. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.07.012