[2-(2-triethoxysilylethyl)benzoyl]ferrocene | 352662-06-7

• 英文名称: [2-(2-triethoxysilylethyl)benzoyl]ferrocene
• CAS: 352662-06-7
• 化学式: C₂₅H₃₂FeO₄Si
• 分子量: 480.459
• InChiKey: UDMKPDJYYPPQOV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  苯甲酰基二茂铁 、 乙烯基三乙氧基硅烷 在 RuH₂(CO)(PPh₃)₃ 作用下， 以 甲苯 为溶剂， 以91%的产率得到[2-(2-triethoxysilylethyl)benzoyl]ferrocene
  参考文献：
  名称：

  Catalytic addition of ferrocenyl ketones to olefins with the aid of Ru(H)2(CO)(PPh3)3

  摘要：

  The catalytic addition reactions of ferrocenyl ketones with terminal olefins in the presence of Ru(H)(2)(CO)(PPh3)(3) as catalyst have been studied. Benzoylferrocene reacts with triethoxyvinylsilane, styrene and vinylferrocene, respectively, to give 1:1 coupling products I-III in high yields. C-H bond cleavage takes place at the carbon atom of the benzene ring at the ortho position of the carbonyl group and C-C bond formation takes place at the terminal carbon atom of the olefins. 2-Furoylferrocene reacts with vinylferrocene to give a 1:1 coupling product IV and the C-H bond cleavage takes place at the carbon atom of the furan ring at the ortho position of the carbonyl group and the C-C bond formation takes place at the terminal carbon atom of vinylferrocene. The new products I-IV have been characterized by elemental analysis, H-1-NMR and MS. The X-ray crystal structure of IV has been determined. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00716-1