CpFe(CO)2(κSe-SeCS2Ph) | 952296-95-6

• 英文名称: CpFe(CO)2(κSe-SeCS2Ph)
• CAS: 952296-95-6
• 化学式: C₁₄H₁₀FeO₂S₂Se
• 分子量: 409.171
• InChiKey: WDNWIMPLTUIFGB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  CpFe(CO)2(κSe-SeCS2Ph) 以 四氢呋喃 为溶剂， 以78%的产率得到CpFe(CO)(κ2S,Se-SeCS2Ph)
  参考文献：
  名称：

  Synthesis and structures of CpFe(CO)2(κE-ECS2Ph) and [CpFe(CO)(κ2S,E-ECS2Ph)] (E=S, Se)

  摘要：

  The iron trithiocarbonato complex CpFe(CO)(2)(kappa S-SCS2Ph) (1a) and its selenodithiocarbonato, analogue CpFe(CO)(2)(kappa Se-SeCS2Ph) (1b) were generated by room temperature reactions of (mu-E-x)[CpFe(CO)(2)](2) (E = S; x = 2, 3. E = Se; x = 1) with PhSC(S)Cl. These compounds can be converted into the complexes CpFe(Co)(kappa S-2,E-ECS2Ph) [E = S (2a), Se (2b)], in which the trithiocarbonato or the selenodithiocarbonato ligand is bonded to the iron in a chelate form, under photolytic conditions. The composition and structure of all products have been verified by elemental analyses, IR and H-1 NMR spectroscopies. The crystal structures for compounds la, 1b, and 2b show a three-legged piano-stool configuration at Fe in each complex. The spectroscopic and structural data in this work are commensurate with the electronic factor of the S- and Se-donor ligands. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.04.010
• 作为产物：
  描述：

  氯代二硫代甲酸苯基酯 、 (μ-Se)[CpFe(CO)2]2 以 乙醚 为溶剂， 以83%的产率得到CpFe(CO)2(κSe-SeCS2Ph)
  参考文献：
  名称：

  Synthesis and structures of CpFe(CO)2(κE-ECS2Ph) and [CpFe(CO)(κ2S,E-ECS2Ph)] (E=S, Se)

  摘要：

  The iron trithiocarbonato complex CpFe(CO)(2)(kappa S-SCS2Ph) (1a) and its selenodithiocarbonato, analogue CpFe(CO)(2)(kappa Se-SeCS2Ph) (1b) were generated by room temperature reactions of (mu-E-x)[CpFe(CO)(2)](2) (E = S; x = 2, 3. E = Se; x = 1) with PhSC(S)Cl. These compounds can be converted into the complexes CpFe(Co)(kappa S-2,E-ECS2Ph) [E = S (2a), Se (2b)], in which the trithiocarbonato or the selenodithiocarbonato ligand is bonded to the iron in a chelate form, under photolytic conditions. The composition and structure of all products have been verified by elemental analyses, IR and H-1 NMR spectroscopies. The crystal structures for compounds la, 1b, and 2b show a three-legged piano-stool configuration at Fe in each complex. The spectroscopic and structural data in this work are commensurate with the electronic factor of the S- and Se-donor ligands. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.04.010

文献信息

• Photochemical substitution of a single CO ligand of CpFe(CO)2SeC(Y)Y′Ar [(Y)Y′ = (O)O, (S)O and (S)S] by EPh3 (E = P, As, Sb)
  作者：Mohammad El-khateeb、Mohammad Harb、Alaa Mansour、Sammer Yousuf

  DOI：10.1016/j.ica.2018.09.063

  日期：2019.2

  Abstract New iron complexes containing selenocarbonato, selenothiocarbonato and selenodithiocarbonato ligands in addition to CO/EPh3 mixed ligands are synthesized and characterized. CpFe(CO)(EPh3)SeC(Y)Y′Ar [(Y)Y′ = (O)O; Ar = C6H5 (1). (Y)Y′ = (S)O; Ar = 4-C6H4Cl (2). (Y)Y′ = (S)S; Ar = C6H5 (3). E = P (a), As (b), Sb (c)] are accessible from the reactions of CpFe(CO)2SeC(Y)Y′Ar with EPh3 under photolytic

  摘要合成并表征了新的铁配合物，该配合物还含有硒代碳原子，硒代硫代碳原子和硒代二硫代碳原子的配体以及CO / EPh3混合配体。CpFe（CO）（EPh3）SeC（Y）Y'Ar [（Y）Y'=（O）O; Ar ＝ C 6 H 5（1）。（Y）Y'=（S）O; Ar ＝ 4-C 6 H 4 Cl（2）。（Y）Y'=（S）S; Ar ＝ C 6 H 5（3）。E = P（a），As（b），Sb（c）]可在光解条件下从CpFe（CO）2SeC（Y）Y'Ar与EPh3的反应获得。新的配合物已通过各种光谱方法（UV-Vis，IR，1H-，31P-，13C-，77Se-NMR）和元素分析进行​​了表征。单晶X射线晶体结构分析进一步支持了CpFe（CO）（AsPh3）SeC（O）OC6H5（1b）的确定结构。